CF₃C₆H₄C(BO₂C₂(CH₃)4)C(BO₂C₂(CH₃)4)C₆H₄CF₃

Base Information

• Chemical Name: CF₃C₆H₄C(BO₂C₂(CH₃)4)C(BO₂C₂(CH₃)4)C₆H₄CF₃
• CAS No.: 355012-35-0
• Molecular Formula: C₂₈H₃₂B₂F₆O₄
• Molecular Weight: 568.172
• Mol file: 355012-35-0.mol

Synonyms:CF₃C₆H₄C(BO₂C₂(CH₃)4)C(BO₂C₂(CH₃)4)C₆H₄CF₃

Chemical Property of CF₃C₆H₄C(BO₂C₂(CH₃)4)C(BO₂C₂(CH₃)4)C₆H₄CF₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of CF₃C₆H₄C(BO₂C₂(CH₃)4)C(BO₂C₂(CH₃)4)C₆H₄CF₃

There total 2 articles about CF₃C₆H₄C(BO₂C₂(CH₃)4)C(BO₂C₂(CH₃)4)C₆H₄CF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bis(pinacol)diborane (73183-34-3) + 1,2-bis(4-(trifluoromethyl)phenyl)ethyne (119757-51-6) → CF3C6H4C(BO2C2(CH3)4)C(BO2C2(CH3)4)C6H4CF3 (355012-35-0)

Guidance literature:

With tris(norbornene)platinum⁽⁰⁾; Diphenyl-o-tolylphosphin; In toluene; at 20 ℃; for 4.3h; Further Variations:; Reagents; Solvents; Product distribution; Kinetics;

DOI:10.1039/b010225n

Reference yield:

2,3-dimethyl-2,3-butane diol (76-09-5) + 2,2'-bis(1,3,2-benzodioxaborole) (13826-27-2) + 1,2-bis(4-(trifluoromethyl)phenyl)ethyne (119757-51-6) → CF3C6H4C(BO2C2(CH3)4)C(BO2C2(CH3)4)C6H4CF3 + CF3C6H4C(BO2C2(CH3)4)C(BO2C2(CH3)4)C6H4CF3 (355012-35-0)

Guidance literature:

tetrakis(trimethylphosphine)cobalt⁽⁰⁾; In tetrahydrofuran; CF3C6H4C2C6H4CF3 added to stirred soln. of B compd. in THF; Co complex (5 mol%) added; stirred at 80°C for 48 h; treated with pinacol (excess); detd. by GC-MS; cis isomer and small amt. of trans isomer obtained;

DOI:10.1039/b516594f

Reference yield: 74.0%

1-bromo-2-[(Z)-2-bromoethenyl]benzene (153140-75-1) + CF3C6H4C(BO2C2(CH3)4)C(BO2C2(CH3)4)C6H4CF3 (355012-35-0) → C24H14F6 (1383673-35-5)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In tetrahydrofuran; water; at 80 ℃; for 48h; regiospecific reaction; Inert atmosphere;

DOI:10.1002/asia.201200132

upstream raw materials:

bis(pinacol)diborane

1,2-bis(4-(trifluoromethyl)phenyl)ethyne

2,3-dimethyl-2,3-butane diol

2,2'-bis(1,3,2-benzodioxaborole)

Downstream raw materials:

C₂₄H₁₄F₆