6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid

Base Information

• Chemical Name: 6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid
• CAS No.: 1338258-74-4
• Molecular Formula: C₂₈H₂₆O₇
• Molecular Weight: 474.51
• Mol file: 1338258-74-4.mol

Synonyms:6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid

Chemical Property of 6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid

There total 1 articles about 6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

4'-hydroxybiphenyl-4-yl 4-(allyloxy)benzoate (133939-19-2) + Adipic acid dichloride (111-50-2) → 6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid (1338258-74-4)

Guidance literature:

4'-hydroxybiphenyl-4-yl 4-(allyloxy)benzoate; Adipic acid dichloride; With pyridine; In chloroform; at 65 ℃; for 24h;

With sulfuric acid; water; at 20 ℃;

DOI:10.1016/j.polymer.2011.09.002

Reference yield: 86.0%

6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid (1338258-74-4) → 4'-(6-chloro-6-oxohexanoyloxy)biphenyl-4-yl 4-(allyloxy)benzoate (1338258-75-5)

Guidance literature:

With thionyl chloride;

DOI:10.1039/c5nj03065j

Reference yield:

6-(4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yloxy)-6-oxohexanoic acid (1338258-74-4) → 4'-(4-(allyloxy)benzoyloxy)biphenyl-4-yl 6-(perfluorooctanoyloxy)hexahydrofuro[3,2-b]furan-3-yl adipate

Guidance literature:

Multi-step reaction with 3 steps

1: pyridine; thionyl chloride / tetrahydrofuran / 20 - 60 °C

2: pyridine / tetrahydrofuran / 36 h / 65 °C

3: pyridine / tetrahydrofuran / 48 h / 63 °C

With pyridine; thionyl chloride; In tetrahydrofuran;

DOI:10.1016/j.polymer.2011.09.002

upstream raw materials:

4'-hydroxybiphenyl-4-yl 4-(allyloxy)benzoate

Adipic acid dichloride

Downstream raw materials:

4'-(6-chloro-6-oxohexanoyloxy)biphenyl-4-yl 4-(allyloxy)benzoate