benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

Base Information

Chemical Name:benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside
CAS No.:434948-87-5
Molecular Formula:C₂₄H₂₇NO₆
Molecular Weight:425.481
Hs Code.:

Synonyms:benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

Suppliers and Price of benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

There total 4 articles about benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 107-93-7
(E)-but-2-enoic acid

: 195006-98-5
benzyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-β-D-allopyranoside

: 434948-87-5
benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

Guidance literature:: With trichloroacetic acid pentachlorophenyl ester; triethylamine; In tetrahydrofuran; at 20 ℃; for 8h;
DOI:10.1016/S0957-4166(01)00562-6

Reference yield:

: 434949-21-0
benzyl 2-amino-(R)-4,6-O-benzylidene-2-deoxy-2-N-3-O-methylidene-2-N-(trans-3-phenyl-2-propenoyl)-β-D-allopyranoside

: 434948-87-5
benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 20 °C

2: sodium borohydride / tetrahydrofuran / 20 °C

3: 90 percent / triethylamine; pentachlorophenol trichloroacetate / tetrahydrofuran / 8 h / 20 °C

With sodium tetrahydroborate; trichloroacetic acid pentachlorophenyl ester; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0957-4166(01)00562-6

Reference yield:

: 434948-85-3
benzyl (R)-4,6-O-benzylidene-2-deoxy-2-(trans-3-phenyl-2-propenamido)-β-D-allopyranoside

: 434948-87-5
benzyl (R)-4,6-O-benzylidene-2-(trans-2-butenamido)-2-deoxy-β-D-allopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / NaOH; tetrabutylammonium bromide / CH₂Cl₂; H₂O / 48 h / Heating

2: 85 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 20 °C

3: sodium borohydride / tetrahydrofuran / 20 °C

4: 90 percent / triethylamine; pentachlorophenol trichloroacetate / tetrahydrofuran / 8 h / 20 °C

With sodium hydroxide; sodium tetrahydroborate; trichloroacetic acid pentachlorophenyl ester; tetrabutylammomium bromide; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; water;
DOI:10.1016/S0957-4166(01)00562-6