1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol

Base Information

• Chemical Name: 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol
• CAS No.: 695177-55-0
• Molecular Formula: C₂₀H₁₉NO₆
• Molecular Weight: 369.374

Synonyms:1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol

Chemical Property of 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol

There total 2 articles about 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-arabino-hex-1-enitol (110522-37-7,124579-04-0,128442-04-6,124579-02-8) → 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol (695177-55-0)

Guidance literature:

1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-arabino-hex-1-enitol; With nitric acid; acetic anhydride;

With triethylamine; In dichloromethane;

DOI:10.1055/s-2004-817790

Reference yield:

benzyl bromide (100-39-0) → 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol (695177-55-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: NaH / dimethylformamide

2.1: HNO₃; Ac₂O

2.2: Et₃N / CH₂Cl₂

With nitric acid; acetic anhydride; sodium hydride; In N,N-dimethyl-formamide;

DOI:10.1055/s-2004-817790

Reference yield: 60.0%

thiophenol (108-98-5) + 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol (695177-55-0) → phenyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-1-thio-α,β-D-glucopyranoside (698371-47-0)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; toluene; at 20 ℃; for 0.5h;

DOI:10.1021/ol049729t

upstream raw materials:

1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-arabino-hex-1-enitol

benzyl bromide

Downstream raw materials:

phenyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-1-thio-α,β-D-glucopyranoside

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 695177-55-0 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-nitro-D-arabino-hex-1-enitol

Send

Send

Metric Ton KG G Pound L ML

Send

Send