(4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone

Base Information

• Chemical Name: (4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone
• CAS No.: 1334335-08-8
• Molecular Formula: C₂₀H₁₅NO₂
• Molecular Weight: 301.345
• Mol file: 1334335-08-8.mol

Synonyms:(4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone

Chemical Property of (4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone

There total 1 articles about (4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(4-hydroxy-1,3-phenylene)bis(phenylmethanone) (2589-81-3) → (4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone (1334335-08-8)

Guidance literature:

With ammonia; In methanol; at 20 ℃; for 16h; regioselective reaction; Cooling with ice;

DOI:10.1002/chem.201101694

Reference yield: 91.0%

(4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone (1334335-08-8) → (S)-(3-(amino(phenyl)methyl)-4-hydroxyphenyl)(phenyl)methanone (1334247-40-3)

Guidance literature:

With (R)-3,3'-bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate; di-tert-butyl 1,4-dihydro-2,6-dimethyl-3,5-pyridine-dicarboxylate; In benzene; at 50 ℃; for 72h; optical yield given as %ee; enantioselective reaction; Inert atmosphere; Sealed tube;

DOI:10.1002/chem.201101694

Reference yield:

(4-hydroxy-3-(imino(phenyl)methyl)phenyl)(phenyl)methanone (1334335-08-8) → (3-(amino(phenyl)methyl)-4-hydroxyphenyl)(phenyl)methanone

Guidance literature:

With sodium tetrahydroborate; In methanol; Inert atmosphere;

DOI:10.1002/chem.201101694

upstream raw materials:

(4-hydroxy-1,3-phenylene)bis(phenylmethanone)

Downstream raw materials:

(S)-(3-(amino(phenyl)methyl)-4-hydroxyphenyl)(phenyl)methanone