4,4'-DIMETHYL-2,2'-BIPYRIDINE FERROUS PERCHLORATE

Base Information

• Chemical Name: 4,4'-DIMETHYL-2,2'-BIPYRIDINE FERROUS PERCHLORATE
• CAS No.: 15740-92-8
• Molecular Formula: C36H36Cl2FeN6O8
• Molecular Weight: 438.98
• Mol file: 15740-92-8.mol

Synonyms:Ferrous, tris(4,4-dimethyl-2,2-bipyridine) perchlorate;Iron(2+), tris(4,4-dimethyl-2,2-bipyridine-kappaN1,kappaN1)-, (OC-6-11)-, diperchlorate;

Chemical Property of 4,4'-DIMETHYL-2,2'-BIPYRIDINE FERROUS PERCHLORATE

Chemical Property:

• Boiling Point: 309.3oC at 760 mmHg
• Flash Point: 116.8oC
• PSA: 174.32000
• LogP: 3.18650

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4,4'-DIMETHYL-2,2'-BIPYRIDINE FERROUS PERCHLORATE

There total 2 articles about 4,4'-DIMETHYL-2,2'-BIPYRIDINE FERROUS PERCHLORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(4,4'-dimethyl-2,2'-bipyridine)iron(III) perchlorate → {Fe(4,4'-dimethyl-2,2'-bipyridine)3}(ClO4)2 (15740-92-8)

Guidance literature:

With dihydrogen peroxide; lithium trifluoromethanesulfonate; In water; byproducts: O2; at 25 °C, I=0.50 M (LiCF3SO3), pH=7.50-8.45; buffered H2O2 soln.(pH controlled by use of 0.10 M tris and 0.025 M phosphate buffers) mixed with complex soln. kept at pH 2; not isolated, monitored at 510 nm; Kinetics;

Reference yield:

4,4'-dimethyl-2,2'-bipyridines (1134-35-6) + Ammonium iron sulfate + sodium perchlorate → {Fe(4,4'-dimethyl-2,2'-bipyridine)3}(ClO4)2 (15740-92-8)

Guidance literature:

In methanol; methanol soln. ammonium ferrous sulphate and dmbpy mixed, excess NaClO4added;

Reference yield:

neptunyl(VI) perchlorate + {Fe(4,4'-dimethyl-2,2'-bipyridine)3}(ClO4)2 (15740-92-8) → [tris(4,4'-dimethyl-2,2'-bipyridine)iron(III)] (34032-03-6) + neptunium(V) (86954-34-9)

Guidance literature:

In perchloric acid; Np(ClO4)6 was reacted with Fe-complex at 1.0, 12.0, 25.0 and 35.0°C in aq. HClO4; Kinetics;

DOI:10.1021/ic50225a074

upstream raw materials:

4,4'-dimethyl-2,2'-bipyridines

Downstream raw materials:

[tris(4,4'-dimethyl-2,2'-bipyridine)iron(III)]

neptunium(V)

Refernces

• 1、 Macartney, D. H.,McAuley, A.. "The oxidation of a nickel(II) oxime complex by polypyridine iron(III) ions in acidic aqueous media. Formation of a Ni(IV) species". . p. 103 - 108. Retrieved 2007/10/02.