(((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane

Base Information

Chemical Name:(((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane
CAS No.:1228675-57-7
Molecular Formula:C₂₄H₄₂O₂Si₂
Molecular Weight:418.767
Hs Code.:

Synonyms:(((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane

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Chemical Property of (((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane

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Technology Process of (((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane

There total 1 articles about (((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1228675-56-6
(((2R,3R)-1-(benzyloxy)-3-methylpent-4-en-2-yl)oxy)(tert-butyl)dimethylsilane

: 1066-54-2
trimethylsilylacetylene

: 1228675-57-7
(((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane

Guidance literature:: (((2R,3R)-1-(benzyloxy)-3-methylpent-4-en-2-yl)oxy)(tert-butyl)dimethylsilane; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 20 ℃; for 2.5h; Inert atmosphere;

With trimethylamine-N-oxide; In tetrahydrofuran; dichloromethane; at 0 - 20 ℃; for 0.5h; Inert atmosphere;

trimethylsilylacetylene; regioselective reaction; Further stages;
DOI:10.1021/ja102888f

Reference yield: 48.0%

: 1228675-62-4
(2S,3R,4R)-1-((4-methoxybenzyl)oxy)-2,4-dimethylhex-5-en-3-ol

: 1228675-57-7
(((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane

: 1228675-70-4
(2R,3R,6S,8R,9R)-2-((benzyloxy)methyl)-8-((S)-1-((4-methoxybenzyl)oxy)propan-2-yl)-3,9-dimethyl-1,7-dioxaspiro[5.5]undecane

Guidance literature:: (((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane; With titanium(IV) isopropylate; In toluene; at 20 ℃; Inert atmosphere;

With cyclopentylmagnesium chloride; In diethyl ether; toluene; at -78 - -30 ℃; for 3h; Inert atmosphere;

(2S,3R,4R)-1-((4-methoxybenzyl)oxy)-2,4-dimethylhex-5-en-3-ol; stereoselective reaction; Further stages;
DOI:10.1021/ja102888f

Reference yield: 43.0%

: 1228675-57-7
(((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane

: 851676-60-3
(2S,3Z)-2-methylpent-3-ene-1-ol

: 1228675-71-5
(2R,3R,6S,9S,11S)-2-((benzyloxy)methyl)-3,9,11-trimethyl-1,7-dioxaspiro[5.5]undecane

Guidance literature:: (((2R,3R)-1-(benzyloxy)-3-methyl-7-(trimethylsilyl)hept-6-yn-2-yl)oxy)(tert-butyl)dimethylsilane; With titanium(IV) isopropylate; In toluene; at 20 ℃; Inert atmosphere;

With cyclopentylmagnesium chloride; In diethyl ether; toluene; at -78 - -30 ℃; for 3h; Inert atmosphere;

(2S,3Z)-2-methylpent-3-ene-1-ol; stereoselective reaction; Further stages;
DOI:10.1021/ja102888f