(E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate

Base Information

Chemical Name:(E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate
CAS No.:1378249-86-5
Molecular Formula:C₂₈H₄₀O₂Si
Molecular Weight:436.71
Hs Code.:

Synonyms:(E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate

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Chemical Property of (E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate

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Technology Process of (E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate

There total 4 articles about (E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1015699-55-4
C₁₆H₂₉BO₂

: 1378249-66-1
2-(((3S,4E)-5-dimethyl(phenyl)silyl-1-phenyl-4-hexen-3-yl)oxy)-5,5-dimethyl-1,3,2-dioxaphosphinane-2-oxide

: 1378249-86-5
(E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate

Guidance literature:: With potassium methanolate; copper (I) acetate; In toluene; at 25 - 80 ℃; for 8h; optical yield given as %ee; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ja302520h

Reference yield:

: 1189125-30-1
(S)-1-phenylhex-4-yn-3-ol

: 1378249-86-5
(E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: diethylzinc; copper(l) cyanide / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

2.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / tetrahydrofuran / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

3.1: potassium methanolate; copper (I) acetate / toluene / 8 h / 25 - 80 °C / Inert atmosphere

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; potassium methanolate; diethylzinc; copper(l) cyanide; copper (I) acetate; In tetrahydrofuran; toluene;
DOI:10.1021/ja302520h

Reference yield:

: 63721-05-1
methyl 3,3-dimethyl-4-penteneoate

: 1378249-86-5
(E)-methyl 6-(dimethylphenylsilyl)-3,3,6-trimethyl-10-phenyl-7-decenoate

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran / 1 h / 60 °C / Inert atmosphere

2: potassium methanolate; copper (I) acetate / toluene / 8 h / 25 - 80 °C / Inert atmosphere

With potassium methanolate; copper (I) acetate; In tetrahydrofuran; toluene;
DOI:10.1021/ja302520h