[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)

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Chemical Name:[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)
CAS No.:1244778-29-7
Molecular Formula:C₆₃H₆₀N₄NiO
Molecular Weight:947.886
Hs Code.:

Synonyms:[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)

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Chemical Property of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)

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Technology Process of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)

There total 1 articles about [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 952190-21-5
[Ni((3,5-di-tert-butylphenyl)2(Ph)(HCC)C₂₀H₈N₄)]

: 6919-61-5
N-methoxy-N-methylbenzamide

: 1244778-29-7
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)

Guidance literature:: With LiN(Si(CH₃)3)2; In tetrahydrofuran; (inert atm.); addn. of of benzamide deriv. and then lithium amide deriv.in THF to degassed soln. of porpyrin deriv. in THF, stirring at room te mp. for 1 h; addn. of aq. NH4Cl, extn. (CH2Cl2), washing with H2O, chromy. (silica gel, light petroleum ether/CH2Cl2 (4:1)), NMR and MS;
DOI:10.1039/c003715j

Reference yield: 30.0%

: 1309441-71-1
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

: 1244778-29-7
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)

: 1244778-30-0
C₁₂₁H₁₁₆N₈Ni₂O

Guidance literature:: [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II); [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II); With lithium hexamethyldisilazane; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

With ammonium chloride; In tetrahydrofuran; water; Inert atmosphere;
DOI:10.1039/c003715j

Reference yield: 30.0%

: 1309441-71-1
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

: 1244778-29-7
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(benzoylethynyl)porphynato]nickel(II)

: 1244778-30-0
[Ni₂((3,5-di-tert-butylphenyl)2(Ph)C₂₀H₈N₄(CC)CH(OH)CCC₂₀H₈N₄(Ph)(3,5-di-tert-butylphenyl)2)]

Guidance literature:: With LiN(Si(CH₃)3)2; In tetrahydrofuran; (inert atm.); addn. of lithium amide deriv. in THF to soln. of porpyrin derivs. in dry THF, stirring at room temp. for 1 h; addn. of aq. NH4Cl, extn. (CH2Cl2), washing with H2O, chromy. (silica gel, light petroleum ether/CH2Cl2 (2:1)), NMR and MS;
DOI:10.1039/c003715j