[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

Base Information

Chemical Name:[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)
CAS No.:1309441-71-1
Molecular Formula:C₅₈H₅₆N₄Ni
Molecular Weight:867.799
Hs Code.:

Synonyms:[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

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Chemical Property of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

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Technology Process of [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

There total 1 articles about [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1244778-18-4
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylbutadiynyl)porphynato]nickel(II)

: 1309441-71-1
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;
DOI:10.1039/c003715j

Reference yield: 95.0%

: 1050506-23-4
mono(trihexylsilyl)acetylene

: 1309441-71-1
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

: 1244778-19-5
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-(trihexylsilylhexatriynyl)porphynato]nickel(II)

Guidance literature:: With CuCl; (CH₃)2NCH₂CH₂N(CH₃)2; air; In tetrahydrofuran; CH₂Cl₂; stirring soln. of porpyrin deriv. and silylacetylene deriv. in CH2Cl2 and THF under dry air, addn. of copper chloride and amine deriv., stirringfor 4 h; filtration through silica, chromy. (silica gel, light petroleum ether/CH2Cl2 (10:1)) under N2, NMR and MS;
DOI:10.1039/c003715j

Reference yield: 63.0%

: 1244778-24-2
[Ni((3,5-di-tert-butylphenyl)2(Ph)(HCO)C₂₀H₈N₄)]

: 1309441-71-1
[5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II)

: 1244778-27-5
C₁₁₃H₁₁₂N₈Ni₂O

Guidance literature:: [Ni((3,5-di-tert-butylphenyl)2(Ph)(HCO)C₂₀H₈N₄)]; [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-butadiynylporphynato]nickel(II); With lithium hexamethyldisilazane; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

With ammonium chloride; In tetrahydrofuran; water; Inert atmosphere;
DOI:10.1039/c003715j