1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene

Base Information

Chemical Name:1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene
CAS No.:653588-34-2
Molecular Formula:C₃₈H₃₀F₆FeO₂P₂
Molecular Weight:764.329
Hs Code.:

Synonyms:1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene

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Chemical Property of 1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene

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Technology Process of 1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene

There total 1 articles about 1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 653588-29-5
1-bromo-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene

: 653588-31-9
ClP(C₆⁽²⁾H₄OC⁽²⁾H₃)2

: 653588-34-2
1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; under N2; soln. of N-BuLi in hexane added to soln. of Fe complex in THF at -78°C; stirred at -78°C for 1 h; soln. of phosphine in THF added at -78°C; warmed to room temp.; stirred for 2 h; poured into water; extd. with CH2Cl2; combined org. layer dried (Na2SO4); evapd. under reduced pressure; purified by chromy. (silica gel, CH2Cl2-hexane);
DOI:10.1021/ja037425g

Reference yield:

: 653587-97-4
iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

: 653588-34-2
1-bis(4-methoxyphenyl-d7)phosphino-1'-bis(4-trifluoromethylphenyl)phosphinoferrocene

: 653588-37-5,654642-65-6
(1-bis(4-trifluoromethylphenyl-d7)phosphino-1'-bis(4-methoxyphenyl)phosphinoferrocene)(p-trifluoromethylphenyl)iodopalladium(II)

: 654642-65-6,653588-37-5
(1-bis(4-trifluoromethylphenyl-d7)phosphino-1'-bis(4-methoxyphenyl)phosphinoferrocene)(p-trifluoromethylphenyl)iodopalladium(II)

Guidance literature:: In tetrahydrofuran; in glovebox; soln. of Fe complex in THF added to soln. of Pd complex in THF at room temp.; stirred for 5 min; solvent removed partially under reduced pressure; added dropwise at roomtemp. to stirred pentane; ppt. isolated by filtration (glass fritted fu nnel); elem. anal.; mixt. of two isomers (4.0:1) obtained, total yield 87%;
DOI:10.1021/ja037425g