iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

Base Information

Chemical Name:iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)
CAS No.:653587-97-4
Molecular Formula:C₁₃H₂₀F₃IN₂Pd
Molecular Weight:494.635
Hs Code.:

Synonyms:iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

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Chemical Property of iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

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Technology Process of iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

There total 1 articles about iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 455-13-0
4-Iodobenzotrifluoride

: 32005-36-0
bis(dibenzylideneacetone)-palladium⁽⁰⁾

: 653587-97-4
iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

Guidance literature:: In benzene; in glovebox; TMEDA and CF3C6H4I added at room temp. to mixt. of Pd complex and benzene; stirred at 50°C for 2 h; filtered through diatomaceous earth; most of solvent removed under reduced pressure; ether added; stirred (3 min); supernatant removed by pipet;washing repeated 3 times; ether added; filtered (glass fritted funnel); solid washed with ether; elem. anal.;
DOI:10.1021/ja037425g

Reference yield: 99.0%

: 12150-46-8
1,1'-bis-(diphenylphosphino)ferrocene

: 653587-97-4
iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

: 653587-98-5
(1,1'-bis(diphenylphosphino)ferrocene)(p-trifluoromethylphenyl)iodopalladium(II)

Guidance literature:: In tetrahydrofuran; in glovebox; soln. of Fe complex in THF added to soln. of Pd complex in THF at room temp.; stirred for 5 min; solvent removed partially under reduced pressure; added at room temp. tostirred pentane; ppt. isolated by filtration (glass fritted funnel); el em. anal.;
DOI:10.1021/ja037425g

Reference yield: 92.0%

: 70227-88-2
1,1'-bis(di-para-(trifluoromethyl)phenylphosphino)ferrocene

: 653587-97-4
iodo(N,N,N',N'-tetramethylethylenediamine)(p-trifluoromethylphenyl)palladium(II)

: 653588-00-2
(1,1'-bis(di(4-trifluoromethylphenyl)phosphino)ferrocene)(p-trifluoromethylphenyl)iodopalladium(II)

Guidance literature:: In tetrahydrofuran; in glovebox; THF added to mixt. of Fe complex and Pd complex at room temp.; stirred for 5 min; solvent removed partially under reduced pressure; added dropwise at roomtemp. to stirred pentane; ppt. isolated by filtration (glass fritted fu nnel); elem. anal.;
DOI:10.1021/ja037425g