(E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

Base Information

Chemical Name:(E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane
CAS No.:1622445-92-4
Molecular Formula:C₂₃H₃₄OSSi₂
Molecular Weight:414.759
Hs Code.:

Synonyms:(E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

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Chemical Property of (E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

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Technology Process of (E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

There total 3 articles about (E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 766-77-8
Dimethylphenylsilane

: 130659-34-6
tert-butyldimethyl((3-(phenylthio)prop-2-yn-1-yl)oxy)silane

: 1622445-91-3
(Z)-tert-butyl((3-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

: 1622445-92-4
(E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

Guidance literature:: With C₁₁H₇Co₂O₇; In dichloromethane; 1,2-dichloro-ethane; at 80 ℃; for 2h; regioselective reaction;
DOI:10.1002/ejoc.201402577

Reference yield:

: 89005-19-6
3-(phenylsulfanyl)propargyl alcohol

: 1622445-91-3
(Z)-tert-butyl((3-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

: 1622445-92-4
(E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole / dichloromethane / 2 h / 0 - 20 °C

2: C₁₁H₇Co₂O₇ / dichloromethane; 1,2-dichloro-ethane / 2 h / 80 °C

With 1H-imidazole; C₁₁H₇Co₂O₇; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1002/ejoc.201402577

Reference yield:

: 1212-08-4
S-Phenyl benzenethiosulfonate

: 1622445-91-3
(Z)-tert-butyl((3-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

: 1622445-92-4
(E)-tert-butyl((2-(dimethyl(phenyl)silyl)-3-(phenylthio)allyl)oxy)dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 2 h / -50 - -20 °C

2.1: 1H-imidazole / dichloromethane / 2 h / 0 - 20 °C

3.1: C₁₁H₇Co₂O₇ / dichloromethane; 1,2-dichloro-ethane / 2 h / 80 °C

With 1H-imidazole; n-butyllithium; C₁₁H₇Co₂O₇; In tetrahydrofuran; hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1002/ejoc.201402577