((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

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Chemical Name:((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane
CAS No.:1415456-31-3
Molecular Formula:C₂₉H₅₂O₄Si
Molecular Weight:492.815
Hs Code.:

Synonyms:((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

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Chemical Property of ((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

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Technology Process of ((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

There total 9 articles about ((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1415456-08-4
1,5-dimethoxy-6-(3-methylbut-2-en-1-yl)cyclohexa-1,4-diene

: 1415456-30-2
((5-((2S,3R)-3-(bromomethyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

: 1415456-31-3
((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

Guidance literature:: 1,5-dimethoxy-6-(3-methylbut-2-en-1-yl)cyclohexa-1,4-diene; With sec.-butyllithium; In cyclohexane; at -78 - -30 ℃; for 1.75h; Inert atmosphere;

((5-((2S,3R)-3-(bromomethyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane; In tetrahydrofuran; cyclohexane; at -78 - -40 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ja312150d

Reference yield:

: 37567-78-5
1,5-dimethoxy-1,4-cyclohexadiene

: 1415456-31-3
((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: tert.-butyl lithium; barium(II) iodide / pentane; tetrahydrofuran / 1 h / -78 °C

1.2: 2.25 h

2.1: sec.-butyllithium / cyclohexane; tetrahydrofuran / 2.33 h / -78 - -30 °C

2.2: 2 h / -78 - -35 °C

With barium(II) iodide; tert.-butyl lithium; sec.-butyllithium; In tetrahydrofuran; cyclohexane; pentane;

Reference yield:

: 1415456-29-9
5-((2S,3R)-3-(bromomethyl)-2-methyloxiran-2-yl)-2-methylpentan-2-ol

: 1415456-31-3
((5-((2S,3S)-3-((2,6-dimethoxy-1-(3-methylbut-2-en-1-yl)cyclohexa-2,5-dien-1-yl)methyl)-2-methyloxiran-2-yl)-2-methylpentan-2-yl)oxy)triethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 2.5 h / 20 °C

2.1: sec.-butyllithium / cyclohexane; tetrahydrofuran / 2.33 h / -78 - -30 °C

2.2: 2 h / -78 - -35 °C

With 1H-imidazole; sec.-butyllithium; In tetrahydrofuran; cyclohexane; N,N-dimethyl-formamide;