(1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde

Base Information

• Chemical Name: (1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde
• CAS No.: 1187618-40-1
• Molecular Formula: C₃₄H₅₄O₉Si
• Molecular Weight: 634.883

Synonyms:(1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde

Chemical Property of (1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde

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Technology Process of (1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde

There total 1 articles about (1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-1-((3S,5S)-5-hydroxymethyl-3,5-bis-methoxymethoxy-2,6,6-trimethyl-cyclohex-1-enyl)-4-(4-methoxy-benzyloxy)-hex-2-en-1-ol → (1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde (1187618-40-1)

Guidance literature:

With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1016/j.tet.2009.04.021

Reference yield:

(1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde (1187618-40-1) + acetylenemagnesium bromide (4301-14-8) → C36H56O9Si (1187618-41-2)

Guidance literature:

(1S,5S)-3-[(E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-hex-2-enoyl]-1,5-bis-methoxymethoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde; acetylenemagnesium bromide; In tetrahydrofuran; at 0 - 20 ℃; for 17.0833h;

With water; In tetrahydrofuran; diethyl ether; at 20 ℃;

DOI:10.1016/j.tet.2009.04.021

Downstream raw materials:

C₃₆H₅₆O₉Si

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