[(aniline)cobalt(N⁽²⁾,N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate

Base Information

• Chemical Name: [(aniline)cobalt(N⁽²⁾,N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate
• CAS No.: 101224-78-6
• Molecular Formula: C₁₈H₂₉CoN₅O₂*ClO₄
• Molecular Weight: 505.904

Synonyms:[(aniline)cobalt(N⁽²⁾,N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate

Chemical Property of [(aniline)cobalt(N⁽²⁾,N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate

Chemical Property:

Purity/Quality:

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Technology Process of [(aniline)cobalt(N⁽²⁾,N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate

There total 1 articles about [(aniline)cobalt(N⁽²⁾,N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

[H2OCo(N(2),N(2')-propanediylbis(2,3-butanodione 2-imine 3-oximate)(1-))CH3]ClO4 + aniline (62-53-3) → [(aniline)cobalt(N(2),N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate (101224-78-6)

Guidance literature:

In water; mixture is stirred until an orange suspn. is formed; a bright orange powder is collected and washed with Et2O;

Reference yield: 93.0%

[(aniline)cobalt(N(2),N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate (101224-78-6) + tris(p-dimethylaminophenyl)phosphine (1104-21-8) → [P(C6H4N(CH3)2)3Co(ONC(CH3)C(CH3)N(CH2)3NC(CH3)C(CH3)NOH)CH3](1+)*ClO4(1-) = [P(C6H4N(CH3)2)3Co(C11H19N4O2)CH3]ClO4 (101224-74-2)

Guidance literature:

With MgSO₄; In dichloromethane; MgSO4 added to soln. of (C6H5NH2Co(ONC(CH3)C(CH3)N(CH2)3NC(CH3)C(CH3)NOH)CH3)ClO4; stirred; filtered; P(4-Me2NPh)3 added; filtrate poured into stirred petroleum ether; supernatant decanted; oil dissolved in acetone;P(4-Me2NPh)3 added; after a few min diethyl ether added; ppt. washed (diethyl ether);

Reference yield: 87.0%

[(aniline)cobalt(N(2),N(2')-propanediylbis(2,3-butanedione 2-imine3-oxime))(methyl)] perchlorate (101224-78-6) + Diphenylvinylphosphine (2155-96-6) → [P(CHCH2)(C6H5)2Co(ONC(CH3)C(CH3)N(CH2)3NC(CH3)C(CH3)NOH)CH3](1+)*ClO4(1-) = [P(CHCH2)(C6H5)2Co(C11H19N4O2)CH3]ClO4 (101224-76-4)

Guidance literature:

With MgSO₄; In dichloromethane; MgSO4 added to soln. of (C6H5NH2Co(ONC(CH3)C(CH3)N(CH2)3NC(CH3)C(CH3)NOH)CH3)ClO4; stirred; filtered; PViPh2 added; filtrate poured into stirred petroleum ether; supernatant decanted; oil dissolved in acetone; PViPh2 added; after a few min diethyl ether added; ppt. washed (diethyl ether);

upstream raw materials:

aniline

Downstream raw materials:

[P(CHCH₂)(C₆H₅)2Co(ONC(CH₃)C(CH₃)N(CH₂)3NC(CH₃)C(CH₃)NOH)CH₃]⁽¹⁺⁾*ClO₄^(1-) = [P(CHCH₂)(C₆H₅)2Co(C₁₁H₁₉N₄O₂)CH₃]ClO₄

[P(CH(CH₃)2)(C₆H₅)2Co(ONC(CH₃)C(CH₃)N(CH₂)3NC(CH₃)C(CH₃)NOH)CH₃]⁽¹⁺⁾*ClO₄^(1-) = [P(C₃H₇)(C₆H₅)2Co(C₁₁H₁₉N₄O₂)CH₃]ClO₄

[P(C₆H₁₁)(C₆H₅)2Co(ONC(CH₃)C(CH₃)N(CH₂)3NC(CH₃)C(CH₃)NOH)CH₃]⁽¹⁺⁾*ClO₄^(1-) = [P(C₆H₁₁)(C₆H₅)2Co(C₁₁H₁₉N₄O₂)CH₃]ClO₄

[P(C₆H₄N(CH₃)2)3Co(ONC(CH₃)C(CH₃)N(CH₂)3NC(CH₃)C(CH₃)NOH)CH₃]⁽¹⁺⁾*ClO₄^(1-) = [P(C₆H₄N(CH₃)2)3Co(C₁₁H₁₉N₄O₂)CH₃]ClO₄

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