(dimethylphenylsilyl)dicyclohexylphosphine

Base Information

• Chemical Name: (dimethylphenylsilyl)dicyclohexylphosphine
• CAS No.: 950922-31-3
• Molecular Formula: C₂₀H₃₃PSi
• Molecular Weight: 332.541
• Mol file: 950922-31-3.mol

Synonyms:(dimethylphenylsilyl)dicyclohexylphosphine

Chemical Property of (dimethylphenylsilyl)dicyclohexylphosphine

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (dimethylphenylsilyl)dicyclohexylphosphine

There total 1 articles about (dimethylphenylsilyl)dicyclohexylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

phenyldimethylsilyl chloride (768-33-2) + chlorodicyclohexylphosphane (16523-54-9) → (dimethylphenylsilyl)dicyclohexylphosphine (950922-31-3)

Guidance literature:

phenyldimethylsilyl chloride; With lithium; In tetrahydrofuran; at -13 - 0 ℃; for 19h; sonication;

chlorodicyclohexylphosphane; In tetrahydrofuran; hexane; at 0 ℃; for 2h; Further stages.;

DOI:10.1039/b706137d

Reference yield: 92.0%

(dimethylphenylsilyl)dicyclohexylphosphine (950922-31-3) + dimethyl cis-but-2-ene-1,4-dioate (624-48-6) → 2-dicyclohexylphosphinoylsuccinic acid dimethyl ester (1128230-37-4)

Guidance literature:

(dimethylphenylsilyl)dicyclohexylphosphine; dimethyl cis-but-2-ene-1,4-dioate; With Pd(2-PyCH=NPh)(OCOC₆F₅)2; In 1,4-dioxane; water; at 60 ℃; for 16h; Inert atmosphere;

With dihydrogen peroxide; In 1,4-dioxane; water; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol8028466

Reference yield: 85.0%

(dimethylphenylsilyl)dicyclohexylphosphine (950922-31-3) + (E)-1-phenyl-2-buten-1-one (35660-91-4,35845-66-0,495-41-0) → 3-dicyclohexylphosphinoyl-1-phenylbutan-1-one (1128230-10-3)

Guidance literature:

(dimethylphenylsilyl)dicyclohexylphosphine; (E)-1-phenyl-2-buten-1-one; With Pd(2-PyCH=NPh)(OCOC₆F₅)2; In 1,4-dioxane; water; at 60 ℃; for 16h; Inert atmosphere;

With dihydrogen peroxide; In 1,4-dioxane; water; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol8028466

upstream raw materials:

phenyldimethylsilyl chloride

chlorodicyclohexylphosphane

Downstream raw materials:

3-(3-dicyclohexylphosphinoyl-3-phenylpropionyl)oxazolidin-2-one

3-(3-dicyclohexylphosphinoylheptanoyl)oxazolidin-2-one

(1-dicyclohexylphosphinoyl-2-nitroethyl)benzene

3-dicyclohexylphosphinoyl-1,3-diphenylpropan-1-one