2-dicyclohexylphosphinoylsuccinic acid dimethyl ester

Base Information

• Chemical Name: 2-dicyclohexylphosphinoylsuccinic acid dimethyl ester
• CAS No.: 1128230-37-4
• Molecular Formula: C₁₈H₃₁O₅P
• Molecular Weight: 358.415
• Mol file: 1128230-37-4.mol

Synonyms:2-dicyclohexylphosphinoylsuccinic acid dimethyl ester

Chemical Property of 2-dicyclohexylphosphinoylsuccinic acid dimethyl ester

Chemical Property:

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Technology Process of 2-dicyclohexylphosphinoylsuccinic acid dimethyl ester

There total 2 articles about 2-dicyclohexylphosphinoylsuccinic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(dimethylphenylsilyl)dicyclohexylphosphine (950922-31-3) + dimethyl cis-but-2-ene-1,4-dioate (624-48-6) → 2-dicyclohexylphosphinoylsuccinic acid dimethyl ester (1128230-37-4)

Guidance literature:

(dimethylphenylsilyl)dicyclohexylphosphine; dimethyl cis-but-2-ene-1,4-dioate; With Pd(2-PyCH=NPh)(OCOC₆F₅)2; In 1,4-dioxane; water; at 60 ℃; for 16h; Inert atmosphere;

With dihydrogen peroxide; In 1,4-dioxane; water; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol8028466

Reference yield: 85.0%

(dimethylphenylsilyl)dicyclohexylphosphine (950922-31-3) + dimethylfumarate (624-49-7) → 2-dicyclohexylphosphinoylsuccinic acid dimethyl ester (1128230-37-4)

Guidance literature:

(dimethylphenylsilyl)dicyclohexylphosphine; dimethylfumarate; With Pd(2-PyCH=NPh)(OCOC₆F₅)2; In 1,4-dioxane; water; at 60 ℃; for 16h; Inert atmosphere;

With dihydrogen peroxide; In 1,4-dioxane; water; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol8028466

upstream raw materials:

(dimethylphenylsilyl)dicyclohexylphosphine

dimethyl cis-but-2-ene-1,4-dioate

dimethylfumarate