ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside

Base Information

• Chemical Name: ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside
• CAS No.: 302905-14-2
• Molecular Formula: C₄₅H₅₂O₇SSi
• Molecular Weight: 765.055

Synonyms:ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside

Chemical Property of ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside

There total 3 articles about ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4,4'-dimethoxytrityl chloride (40615-36-9) + ethyl 6-O-tert-butyldiphenylsilyl-2-thio-β-D-fructofuranoside (302905-13-1) → ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside (302905-14-2)

Guidance literature:

With pyridine; dmap; for 4h;

DOI:10.1021/ja001439u

Reference yield:

tert-butylchlorodiphenylsilane (58479-61-1) → ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside (302905-14-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 74 percent / pyridine / 20 °C

2: 94 percent / pyridine; 4-(dimethylamino)pyridine / 4 h

With pyridine; dmap;

DOI:10.1021/ja001439u

Reference yield:

ethyl 2-thio-β-D-fructofuranoside (80763-61-7) → ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside (302905-14-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 74 percent / pyridine / 20 °C

2: 94 percent / pyridine; 4-(dimethylamino)pyridine / 4 h

With pyridine; dmap;

DOI:10.1021/ja001439u

upstream raw materials:

4,4'-dimethoxytrityl chloride

ethyl 6-O-tert-butyldiphenylsilyl-2-thio-β-D-fructofuranoside

tert-butylchlorodiphenylsilane

ethyl 2-thio-β-D-fructofuranoside

Downstream raw materials:

ethyl 3-O-benzyl-6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside

Sucrose

2,3,3',4,6-penta-O-benzyl-6'-O-tert-butyldiphenylsilyl-1',4'-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)sucrose

methyl [3-O-benzyl-6-O-tert-butyldiphenylsilyl-1,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-β-D-fructofuranosyl]-(1->6)-2,3,4-tri-O-benzyl-αD-mannopyranoside

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 302905-14-2 ethyl 6-O-tert-butyldiphenylsilyl-1-O-(4,4'-dimethoxytriphenyl)methyl-2-thio-β-D-fructofuranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send