Hex-2-ulofuranosyl hexopyranoside

Base Information

• Chemical Name: Hex-2-ulofuranosyl hexopyranoside
• CAS No.: 57-50-1
• Molecular Formula: C12H22O11
• Molecular Weight: 342.3
• Hs Code.: 1701991090
• NSC Number: 406942
• Wikidata: Q103818207
• Mol file: 57-50-1.mol

Synonyms:Hex-2-ulofuranosyl hexopyranoside;2-[3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol;1192061-43-0;BETA-D-FRUCTOFURANOSYL-ALPHA-D-GALACTOPYRANOSIDE;3h-sucrose;BETA-D-[1-13C]FRUCTOFURANOSYL ALPHA-D-GLUCOPYRANOSIDE;2-{[3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy}-6-(hydroxymethyl)oxane-3,4,5-triol;.alpha.-D-Glucopyranoside, .beta.-D-fructofuranosyl;Zucker;MFCD00006626;13322-96-8;(.alpha.-D-Glucosido)-.beta.-D-fructofuranoside;.alpha.-D-Glucopyranosyl .beta.-D-fructofuranoside;.beta.-D-Fructofuranoside, .alpha.-D-glucopyranosyl;.beta.-D-Fructofuranosyl .alpha.-D-glucopyranoside;(Hex)2;Fructofuranoside, .beta.-D;Glucopyranoside, .alpha.-D;SCHEMBL12312;QSPL 117;QSPL 149;SGCUT00130;CHEBI:193884;(2R,3R,4S,5S,6R)-2-[(2S,3S,4S,5R)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol;to_000080;BBL002888;NSC406942;STK378319;AKOS005448523;SY009493;VS-01258;FT-0621912;4F0791E5-05FB-4AEE-92EF-C876AABBC4E1;WLN: T6OTJ CQ DQ EQ F1Q BO- BT5OTJ B1Q CQ DQ E1Q -GLU,FRUC;2-{[3,4-dihydroxy-2,5-bis(hydroxymethyl)tetrahydrofuran-2-yl]oxy}-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

Chemical Property of Hex-2-ulofuranosyl hexopyranoside

Chemical Property:

• Appearance/Colour: White crystalline powder
• Vapor Pressure: 1.79E-22mmHg at 25°C
• Melting Point: 185-187 °C(lit.)
• Refractive Index: 66.5 ° (C=26, H2O)
• Boiling Point: 697.1 °C at 760 mmHg
• Flash Point: 375.4 °C
• PSA: 189.53000
• Density: 1.77 g/cm³
• LogP: -5.39560
• Water Solubility.: 1970 g/L (15℃)
• XLogP3: -3.7
• Hydrogen Bond Donor Count: 8
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 5
• Exact Mass: 342.11621151
• Heavy Atom Count: 23
• Complexity: 395

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Safety Statements: S24/25:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)OC2(C(C(C(O2)CO)O)O)CO)O)O)O)O

Technology Process of Hex-2-ulofuranosyl hexopyranoside

There total 161 articles about Hex-2-ulofuranosyl hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,3,3',4,6-penta-O-benzylsucrose (302905-28-8) → Sucrose (57-50-1)

Guidance literature:

With Amberlite IR-45(OH-); hydrogen; palladium on activated charcoal; In methanol; ethyl acetate; under 5688.78 Torr;

DOI:10.1021/ja001439u

Reference yield: 87.0%

inulin → D-Fructose (57-48-7,18875-34-8) + Sucrose (57-50-1)

Guidance literature:

With niobic acid; In water; at 89.84 ℃; for 2h; Reagent/catalyst; Catalytic behavior; Autoclave; Inert atmosphere;

DOI:10.1021/cm400192q

Reference yield: 43.0%

inulin → mannitol (69-65-8) + D-sorbitol (50-70-4) + Sucrose (57-50-1)

Guidance literature:

With hydrogen; In water; at 89.84 ℃; for 4h; under 15001.5 Torr; Reagent/catalyst; Pressure; Catalytic behavior;

DOI:10.1039/c4ra05939e

upstream raw materials:

UDP-glucose

D-Fructose

Glycolaldehyde

D-raffinose

Downstream raw materials:

5-(methoxymethyl)-2-furaldehyde

levulinic acid methyl ester

methyl β-D-fructofuranoside

methyl α-D-fructofuranoside

Refernces

Synthesis and characterization of NiO and NiFe₂ O₄ nanoparticles obtained by a sucrose-based route

10.1016/j.jpcs.2007.01.051

The research presents a novel and cost-effective method for synthesizing nickel oxide (NiO) and nickel ferrite (NiFe2O4) nanoparticles using sucrose as a chelating agent. The process involves dissolving sucrose and metal nitrates in an aqueous solution, forming a gel upon evaporation, and then heating the gel at various temperatures (300, 600, and 750°C). The study utilized X-ray diffraction (XRD), scanning electron microscopy (SEM), and optical microscopy to characterize the synthesized nanoparticles. The results showed that NiO and NiFe2O4 nanoparticles with high crystallinity and mean sizes ranging from 11 to 36 nm were successfully produced. The particle size of NiO increased with higher synthesis temperatures, while the size of NiFe2O4 nanoparticles remained consistent across different temperatures due to the influence of the heating rate. This method offers a simple, low-cost alternative for producing nanoscale oxide powders with potential technological applications.

Synthesis of regio- and stereospecifically C-deuterated derivatives of glycosidase inhibitors 1-deoxymannonojirimycin and 2,5-dideoxy-2,5-imino-D-mannitol by intramolecular reductive amination employing deuterium gas

10.1016/S0008-6215(98)00159-1

This study focuses on the synthesis of regio- and stereospecifically C-deuterated derivatives of glycosidase inhibitors, namely 1-deoxymannonojirimycin and 2,5-dideoxy-2,5-imino-D-mannitol, using intramolecular reductive amination with deuterium gas. The researchers employed 6-azido-1,3,4-tri-O-benzyl-6-deoxy-D-fructofuranose, obtained from 6,6'-diazido-6,6-dideoxysucrose, which was derived from sucrose. Through controlled hydrogenation with deuterium over Raney nickel, they produced 3,4,6-tri-O-benzyl-1,5-dideoxy-1,5-imino-D-(5-H)mannitol, a partially protected derivative of 1-deoxymannonojirimycin. Further deprotection yielded 1-deoxy-(5-H)mannonojirimycin. Additionally, 2,5-dideoxy-2,5-imino-D-(5-H)mannitol was synthesized from 5-azido-5-deoxy-D-fructopyranose, and 2,5-dideoxy-2,5-imino-D-(5-H)glucitol was obtained from 5-azido-5-deoxy-L-sorbose. The study aimed to introduce deuterium as late as possible in the synthesis process to maximize its incorporation and minimize isotopic scrambling, achieving high yields and selective deuteration.