(η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate

Base Information

Chemical Name:(η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate
CAS No.:165681-30-1
Molecular Formula:C₂₃H₂₀FeP*F₆P
Molecular Weight:528.197
Hs Code.:

(η<sup>6</sup>-Diphenylphosphinobenzene)(η<sup>5</sup>-cyclopentadienyl)iron(II) hexafluorophosphate

Synonyms:(η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate

Chemical Property:

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Technology Process of (η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate

There total 3 articles about (η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: (η6-chlorobenzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate

: 829-85-6
diphenylphosphane

: 165681-30-1
(η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate

Guidance literature:: diphenylphosphane; With n-butyllithium; In diethyl ether; at -30 ℃; for 4h; Inert atmosphere; Schlenk technique;

(η6-chlorobenzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate; In tetrahydrofuran; at -30 - 20 ℃; for 18h; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.jorganchem.2016.02.037

Reference yield:

: ammonium hexafluorophosphate

: 102-54-5,55404-68-7
ferrocene

: 603-35-0
triphenylphosphine

: 165681-30-1
(η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate

: 165681-30-1
η-triphenylphosphine-η-cyclopentadienyliron(II) hexafluorophosphate

Guidance literature:: With aluminium trichloride; aluminium; In water; other Radiation; 0.02 mol metal addn. to arene, Fe- and Al-salts mixt. in 1,2,4-C6H3Cl3 (ratio arene:Fe:AlCl3:Al=1:5:10:10), homogenization (stirring), mixt. irradiation in microwave oven (850 W) for 4 min, ice addn. (AlCl3 decompn.), filtration, filtrate washing (Et2O); filtration, treating with aq. NH4-salt, ppt. filtration off through sinter, washing (i-PrOH, Et2O); total yield 92 %, mono/bis=48/52;
DOI:10.1039/P19950000743

Reference yield:

: ammonium hexafluorophosphate

: 102-54-5,55404-68-7
ferrocene

: 603-35-0
triphenylphosphine

: 165681-30-1
(η⁶-Diphenylphosphinobenzene)(η⁵-cyclopentadienyl)iron(II) hexafluorophosphate

: 165681-30-1
η-triphenylphosphine-η-cyclopentadienyliron(II) hexafluorophosphate

Guidance literature:: With aluminium trichloride; aluminium; In water; other Radiation; 0.02 mol metal addn. to arene, Fe- and Al-salts mixt. in 1,2,4-C6H3Cl3 (ratio arene:Fe:AlCl3:Al=1:5:10:10), homogenization (stirring), mixt. irradiation in microwave oven (850 W) for 4 min, ice addn. (AlCl3 decompn.), filtration, filtrate washing (Et2O); filtration, treating with aq. NH4-salt, ppt. filtration off through sinter, washing (i-PrOH, Et2O); total yield 92 %, mono/bis=48/52;
DOI:10.1039/P19950000743