methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside

Base Information

• Chemical Name: methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside
• CAS No.: 88154-14-7
• Molecular Formula: C₃₀H₃₃ClO₇
• Molecular Weight: 541.041
• Mol file: 88154-14-7.mol

Synonyms:methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside

Chemical Property of methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside

There total 1 articles about methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside (53008-65-4,641635-63-4) + chloroacetyl chloride (79-04-9) → methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside (88154-14-7)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1016/j.carres.2015.10.007

Reference yield: 96.0%

methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside (88154-14-7) → methyl 2,3,4-tri-O-benzyl-D-glucopyranoside (53008-65-4,641635-63-4)

Guidance literature:

With dithiocarbonic acid hydrazide; In acetic acid; for 0.166667h; Ambient temperature;

DOI:10.1016/S0040-4039(00)94532-5

Reference yield:

methyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-α-D-glucopyranoside (88154-14-7) → C30H33N3O7

Guidance literature:

With sodium azide; potassium iodide; In acetone; at 20 ℃; for 24h;

DOI:10.1055/s-0031-1290975

upstream raw materials:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

chloroacetyl chloride

Downstream raw materials:

methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

3-[6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl]prop-1-ene

3-{2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-α-D-glucopyranosyl}prop-1-ene