(Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester

Base Information

Chemical Name:(Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester
CAS No.:1370009-33-8
Molecular Formula:C₄₃H₅₆O₄
Molecular Weight:636.915
Hs Code.:

Synonyms:(Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester

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Chemical Property of (Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester

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Technology Process of (Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester

There total 3 articles about (Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1370009-39-4
(Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-tert-butoxycarbonylvinyl)biphenyl-4-yl ester

: 1370009-33-8
(Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester

Guidance literature:: With trifluoroacetic acid; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1016/j.bmc.2012.01.042

Reference yield:

: 496868-80-5
4-(4'-bromophenyl)-2-(adamantan-1-yl)phenol

: 1370009-33-8
(Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: palladium diacetate; triethylamine; tris-(o-tolyl)phosphine / 1 h / 110 °C / Neat (no solvent)

2: pyridine; dmap / 20 °C

3: trifluoroacetic acid / dichloromethane / 0.5 h / 0 °C

With pyridine; dmap; palladium diacetate; triethylamine; tris-(o-tolyl)phosphine; trifluoroacetic acid; In dichloromethane; 1: Heck reaction;
DOI:10.1016/j.bmc.2012.01.042

Reference yield:

: 7459-33-8
linoleyl chloride

: 1232884-73-9
(E)-3-(3'-adamantan-1-yl-4'-hydroxybiphenyl-4-yl)acrylic acid tert-butyl ester

: 1370009-33-8
(Z,Z)-octadeca-9,12-dienoic acid 3-adamantan-1-yl-4'-((E)-2-carboxyvinyl)-biphenyl-4-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine; dmap / 20 °C

2: trifluoroacetic acid / dichloromethane / 0.5 h / 0 °C

With pyridine; dmap; trifluoroacetic acid; In dichloromethane;
DOI:10.1016/j.bmc.2012.01.042