methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate

Base Information

Chemical Name:methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate
CAS No.:343256-36-0
Molecular Formula:C₁₉H₃₀O₆Si
Molecular Weight:382.529
Hs Code.:

Synonyms:methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate

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Chemical Property of methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate

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Technology Process of methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate

There total 2 articles about methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 124555-63-1
4-methoxy-2-methoxymethoxy benzaldehyde

: 78186-95-5
methyl 2-(tert-butyldimethylsiloxy)-2-(dimethoxyphosphoryl)acetate

: 343256-36-0
methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate

Guidance literature:: With n-butyllithium; diisopropylamine; In tetrahydrofuran; at -78 ℃;
DOI:10.1021/jo010015v

Reference yield:

: 673-22-3
2-Hydroxy-4-methoxybenzaldehyde

: 343256-36-0
methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / iPr₂NEt / tetrahydrofuran / 0 - 20 °C

2: 99 percent / iPr₂NH; n-BuLi / tetrahydrofuran / -78 °C

With n-butyllithium; diisopropylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; 2: Wadsworth-Emmons olefination;
DOI:10.1021/jo010015v

Reference yield: 99.0%

: 343256-36-0
methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate

: 343256-38-2
methyl 2(E)-(hydroxyimino)-3-(4-methoxy-2-O-methoxymethylenoxyphenyl)propanoate

Guidance literature:: methyl 2-{(1,1-dimethylethyl)dimethylsilyloxy}-3-{4-methoxy-2-(O-methoxymethylenoxy)phenyl}prop-2-enoate; With triethylamine hydrofluoride; In methanol;

With hydroxylamine hydrochloride; In methanol; Further stages.;
DOI:10.1021/jo010015v