3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester

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Chemical Name:3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester
CAS No.:913623-00-4
Molecular Formula:C₂₇H₃₄ClNO₁₁
Molecular Weight:584.02
Hs Code.:

Synonyms:3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester

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Chemical Property of 3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester

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Technology Process of 3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester

There total 9 articles about 3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 913622-79-4
3-chloro-2-(5-hexenyl)-4,6-dihydroxybenzoic acid

: 913622-10-3
3-(2-methoxy-3,6-bis(methoxymethoxy)-5-nitrophenyl)propan-1-ol

: 913623-00-4
3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 - 20 ℃; for 10h;
DOI:10.1021/jo061054f

Reference yield:

: 913622-68-1
ethyl 3-(2-methoxy-3,6-bis(methoxymethoxy)phenyl)acrylate

: 913623-00-4
3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: H₂ / Pd/C / ethyl acetate / 12 h

1.2: 3.69 g / DIBAL-H / CH₂Cl₂ / 1 h / 0 °C

2.1: NH₄NO₃; (CF₃CO)2O / acetonitrile / 0.25 h / 20 °C

2.2: 67 percent / LiOH / tetrahydrofuran; methanol; H₂O / 0.08 h

3.1: 82 percent / PPh₃; diisopropyl azodicarboxylate / tetrahydrofuran / 10 h / 0 - 20 °C

With ammonium nitrate; di-isopropyl azodicarboxylate; hydrogen; triphenylphosphine; trifluoroacetic anhydride; palladium on activated charcoal; In tetrahydrofuran; ethyl acetate; acetonitrile; 3.1: Mitsunobu esterification;
DOI:10.1021/jo061054f

Reference yield:

: 824-46-4
methoxyhydroquinone

: 913623-00-4
3-chloro-2-hex-5-enyl-4,6-dihydroxy-benzoic acid 3-(2-methoxy-3,6-bis-methoxymethoxy-5-nitro-phenyl)-propyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 91 percent / NaH

2.1: TMEDA; n-BuLi / tetrahydrofuran / 4 h / 20 °C

2.2: 77 percent / tetrahydrofuran / 2 h

3.1: NaH / toluene / 0.25 h / 20 °C

3.2: 86 percent / toluene / 12 h / 20 °C

4.1: H₂ / Pd/C / ethyl acetate / 12 h

4.2: 3.69 g / DIBAL-H / CH₂Cl₂ / 1 h / 0 °C

5.1: NH₄NO₃; (CF₃CO)2O / acetonitrile / 0.25 h / 20 °C

5.2: 67 percent / LiOH / tetrahydrofuran; methanol; H₂O / 0.08 h

6.1: 82 percent / PPh₃; diisopropyl azodicarboxylate / tetrahydrofuran / 10 h / 0 - 20 °C

With ammonium nitrate; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; di-isopropyl azodicarboxylate; hydrogen; sodium hydride; triphenylphosphine; trifluoroacetic anhydride; palladium on activated charcoal; In tetrahydrofuran; ethyl acetate; toluene; acetonitrile; 6.1: Mitsunobu esterification;
DOI:10.1021/jo061054f