lithium diphenylphosphido borane

Base Information

Chemical Name:lithium diphenylphosphido borane
CAS No.:145130-18-3
Molecular Formula:C₁₂H₁₃BLiP
Molecular Weight:205.961
Hs Code.:

Synonyms:lithium diphenylphosphido borane

Suppliers and Price of lithium diphenylphosphido borane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of lithium diphenylphosphido borane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of lithium diphenylphosphido borane

There total 6 articles about lithium diphenylphosphido borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.6%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 1160717-69-0
(Me₃Si){Ph₂P(BH₃)}C=CH₂

: 7439-93-2
lithium

: 145130-18-3
lithium diphenylphosphido borane

: [(CH₃)3SiC(CH₂)BH₃P(C₆H₅)2Li(C₄H₈O)3]2*2C₄H₈O

Guidance literature:: In tetrahydrofuran; (under Ar, Schlenk); lithium added to THF soln. of B-compound, stirred ultrasonically for 30 min; filtered, solvent removed in vacuo, ppt. washed with light petroleum, crystd. from cold (-30°C) methylcyclohexane with THF;
DOI:10.1039/b822054a

Reference yield:

: 41593-58-2
diphenylphosphineborane

: 145130-18-3
lithium diphenylphosphido borane

Guidance literature:: diphenylphosphineborane; With lithium; In tetrahydrofuran; at 0 ℃; for 4h;

With tertiary butyl chloride; In tetrahydrofuran; for 0.5h;
DOI:10.1002/hlca.200900435

Reference yield:

: 4559-70-0
Diphenylphosphine oxide

: 145130-18-3
lithium diphenylphosphido borane

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / -78 - 20 °C

1.2: 2 h / 0 °C

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / 0 - 20 °C

With n-butyllithium; diisobutylaluminium hydride; In tetrahydrofuran; hexane;
DOI:10.1039/d1cc04996h