2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester

Base Information

• Chemical Name: 2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester
• CAS No.: 909025-39-4
• Molecular Formula: C₂₁H₃₀SSe
• Molecular Weight: 393.495
• Mol file: 909025-39-4.mol

Synonyms:2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester

Chemical Property of 2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester

There total 4 articles about 2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

N-phenylselanylphthalimide (71098-88-9) + (E)-3,7,11-trimethyldodeca-1,6,10-triene-3-thiol (122507-95-3) → 2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester (909025-39-4)

Guidance literature:

In dichloromethane; at -78 - 20 ℃;

DOI:10.1021/ol061381+

Reference yield:

(E)-S-3,7,11-trimethyldodeca-1,6,10-trien-3-yl dimethylcarbamothioate (909025-58-7) → 2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester (909025-39-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 87 percent / LiAlH₄ / diethyl ether / 2 h / Heating

2: 56 percent / CH₂Cl₂ / -78 - 20 °C

With lithium aluminium tetrahydride; In diethyl ether; dichloromethane;

DOI:10.1021/ol061381+

Reference yield:

Farnesol (106-28-5) → 2-(1,5,9-trimethyl-1-vinyl-deca-4,8-diene)-sulfenoselenoic acid phenyl ester (909025-39-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 80 percent / sodium hydride / dimethylformamide; various solvent(s); diethyl ether / 1 h / 60 °C

2: 83 percent / 2.5 h / 140 °C

3: 87 percent / LiAlH₄ / diethyl ether / 2 h / Heating

4: 56 percent / CH₂Cl₂ / -78 - 20 °C

With lithium aluminium tetrahydride; sodium hydride; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/ol061381+

upstream raw materials:

N-phenylselanylphthalimide

(E)-3,7,11-trimethyldodeca-1,6,10-triene-3-thiol

(E)-S-3,7,11-trimethyldodeca-1,6,10-trien-3-yl dimethylcarbamothioate

Farnesol