(2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate

Base Information

Chemical Name:(2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate
CAS No.:1225385-08-9
Molecular Formula:C₃₂H₅₃IO₇Si
Molecular Weight:704.759
Hs Code.:

(2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate

Synonyms:(2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate

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Chemical Property of (2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate

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Technology Process of (2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate

There total 1 articles about (2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1225384-91-7
(2R,4R,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-5-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-3-one

: 123-38-6
propionaldehyde

: 1225385-08-9
(2R,3R,4S,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-3-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-5-yl propionate

Guidance literature:: propionaldehyde; With samarium diiodide; In tetrahydrofuran; at -20 ℃; Inert atmosphere;

(2R,4R,5R,6E,9R,10E)-9-(tert-butyldimethylsilyloxy)-1-(3,4-dimethoxybenzyloxy)-5-hydroxy-11-iodo-2,4,7-trimethylundeca-6,10-dien-3-one; In tetrahydrofuran; at -20 ℃; for 1h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol100693c