(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone

Base Information

Chemical Name:(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone
CAS No.:1154607-05-2
Molecular Formula:C₂₉H₄₂O₃Si₂
Molecular Weight:494.822
Hs Code.:

Synonyms:(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone

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Chemical Property of (3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone

Chemical Property:

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Technology Process of (3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone

There total 1 articles about (3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1154607-08-5
C₃₅H₅₈O₃Si₃

: 1154607-05-2
(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone

Guidance literature:: C₃₅H₅₈O₃Si₃; With pyridinium p-toluenesulfonate; In ethanol; at 20 ℃; for 1h;

With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 0 ℃; for 2h;

Reference yield:

: 4071-88-9
trimethylsilanyl-acetic acid ethyl ester

: 1154607-05-2
(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone

: 1154607-12-1
ethyl (2E)-((3R,5R)-3-{[tert-butyl(diphenyl)silyl]oxy}-5-hydroxy-4-methylenecyclohexylidene)acetate

Guidance literature:: trimethylsilanyl-acetic acid ethyl ester; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone; In tetrahydrofuran; hexane; at -78 ℃; for 4.08333h;

With hydrogenchloride; In ethanol; at 20 ℃;

Reference yield:

: 2916-76-9
methyl (trimethylsilyl)acetate

: 1154607-05-2
(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone

: methyl (2Z)-((3R,5R)-3-{[tert-butyl(diphenyl)silyl]oxy}-5-hydroxy-4-methylenecyclohexylidene)acetate

Guidance literature:: methyl (trimethylsilyl)acetate; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

(3R,5R)-3-{[tert-butyl(dimethyl)silyl]oxy}-5-{[tert-butyl(diphenyl)silyl]oxy}-4-methylenecyclohexanone; In tetrahydrofuran; hexane; for 4.08333h;

With hydrogenchloride; In ethanol; at 20 ℃;