1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal

Base Information

• Chemical Name: 1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal
• CAS No.: 1010696-58-8
• Molecular Formula: C₃₄H₃₅NO₇S₂
• Molecular Weight: 633.786
• Mol file: 1010696-58-8.mol

Synonyms:1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal

Chemical Property of 1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal

There total 11 articles about 1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C34H35NO7S2 → 1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal (1010696-58-8)

Guidance literature:

With sodium hydrogencarbonate; In methanol; at 20 ℃; for 8h;

DOI:10.1021/jo701655v

Reference yield:

C34H35NO7S2 → 1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal (1010696-58-8)

Guidance literature:

With sodium hydrogencarbonate; In methanol; water;

DOI:10.1002/anie.201804602

Reference yield:

C37H39NO7S2 → 1L-(1,2,3',4,5/3,6)-3,3'-di-O-benzyl-3-C-hydroxymethyl-6-nitro-2,3,4,5,6-tetrahydroxycyclohexanecarbaldehyde bis(phenylthio)acetal (1010696-58-8)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid / water / Reflux

2: sodium hydrogencarbonate / water; methanol

With sodium hydrogencarbonate; acetic acid; In methanol; water;

DOI:10.1002/anie.201804602

upstream raw materials:

D-Glucose

benzyl bromide