2-(Methylsulphonyl)phenacyl bromide

Base Information

Chemical Name:2-(Methylsulphonyl)phenacyl bromide
CAS No.:99513-18-5
Molecular Formula:C₉H₉BrO₃S
Molecular Weight:277.139
Hs Code.:
European Community (EC) Number:865-158-2
DSSTox Substance ID:DTXSID201258967

Synonyms:99513-18-5;2-(Methylsulphonyl)phenacyl bromide;2-bromo-1-(2-methylsulfonylphenyl)ethanone;Ethanone, 2-bromo-1-[2-(methylsulfonyl)phenyl]-;SCHEMBL5028957;DTXSID201258967;AKOS000282414;2-Bromo-1-[2-(methylsulfonyl)phenyl]ethanone;2-bromo-1-(2-methanesulfonylphenyl)ethan-1-one;EN300-23329704

Suppliers and Price of 2-(Methylsulphonyl)phenacyl bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2-(Methylsulphonyl)phenacyl bromide

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:275.94558
Heavy Atom Count:14
Complexity:305

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CS(=O)(=O)C1=CC=CC=C1C(=O)CBr

Technology Process of 2-(Methylsulphonyl)phenacyl bromide

There total 5 articles about 2-(Methylsulphonyl)phenacyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 3323-76-0
1-(2-Methanesulfonyl-phenyl)-ethanone

: 99513-18-5
2-bromo-1-(2-(methylsulfonyl)phenyl)ethan-1-one

Guidance literature:: With copper(ll) bromide; In ethyl acetate; at 80 ℃; for 18h;

Reference yield:

: 49639-13-6
2-methylsulfonylbenzoyl chloride

: 99513-18-5
2-bromo-1-(2-(methylsulfonyl)phenyl)ethan-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Mg, CCl₄ / 1.) EtOH, ether, reflux, 3h, 2.) EtOH, ether, reflux, 10 min.

2: 86 percent / conc. H₂SO₄ / aq. acetic acid / 4 h / Heating

3: AlCl₃, Br₂ / CHCl₃

With tetrachloromethane; aluminium trichloride; sulfuric acid; bromine; magnesium; In chloroform; acetic acid;
DOI:10.1002/ardp.19803130704

Reference yield:

: 75473-10-8
2-Mesylbenzoyl-malonsaeurediethylester

: 99513-18-5
2-bromo-1-(2-(methylsulfonyl)phenyl)ethan-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / conc. H₂SO₄ / aq. acetic acid / 4 h / Heating

2: AlCl₃, Br₂ / CHCl₃

With aluminium trichloride; sulfuric acid; bromine; In chloroform; acetic acid;
DOI:10.1002/ardp.19803130704