[(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene

Base Information

• Chemical Name: [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene
• CAS No.: 115764-86-8
• Molecular Formula: C₁₅H₂₉ClSi₃
• Molecular Weight: 329.105
• Mol file: 115764-86-8.mol

Synonyms:[(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene

Chemical Property of [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene

There total 4 articles about [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(trimethylsilyl)dichloromethane (15951-41-4) + phenyldimethylsilyl chloride (768-33-2) → [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene (115764-86-8)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) THF, pentane, Et₂O, hexane, -110 deg C, 3 h, 2.) THF, pentane, Et₂O, hexane, from -110 deg C to RT;

DOI:10.1039/P29930000059

Reference yield:

bis(trimethylsilyl)dichloromethane (15951-41-4) + fluorodimethylphenylsilane (454-57-9) → [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene (115764-86-8)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) hexane, THF, Et₂O, n-pentane, -110 deg C, 2 h, 2.) hexane, THF, Et₂O, n-pentane, a) -110 deg C, 30 min, b) -110 deg C - RT, overnight;

DOI:10.1016/0022-328X(94)88026-3

Reference yield:

bromobenzene (108-86-1,52753-63-6) → [(Chloro-bis-trimethylsilanyl-methyl)-dimethyl-silanyl]-benzene (115764-86-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) Mg / 1.) ether, 2.) ether, RT, 30 min

2: 40percent aq. HF / ethanol / 8 h / Heating

3: 1.) BuLi / 1.) hexane, THF, Et₂O, n-pentane, -110 deg C, 2 h, 2.) hexane, THF, Et₂O, n-pentane, a) -110 deg C, 30 min, b) -110 deg C - RT, overnight

With n-butyllithium; hydrogen fluoride; magnesium; In ethanol;

DOI:10.1016/0022-328X(94)88026-3

upstream raw materials:

bis(trimethylsilyl)dichloromethane

fluorodimethylphenylsilane

phenyldimethylsilyl chloride

bromobenzene

Downstream raw materials:

(dimethylphenylsilyl)bis(trimethylsilyl)methane

(dimethylphenylsilyl)(dimethylsilyl)bis(trimethylsilyl)methane

C₂₂H₃₇BrSi₄

(dimethyltrifluoroacetoxysilyl)(methyldiphenylsilyl)bis(trimethylsilyl)methane