2,4-dinitrobenzyl anion

Base Information

• Chemical Name: 2,4-dinitrobenzyl anion
• CAS No.: 87116-33-4
• Molecular Formula: C₇H₅N₂O₄
• Molecular Weight: 181.128
• Mol file: 87116-33-4.mol

Synonyms:2,4-dinitrobenzyl anion

Chemical Property of 2,4-dinitrobenzyl anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4-dinitrobenzyl anion

There total 3 articles about 2,4-dinitrobenzyl anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4-dinitrotoluene (121-14-2) → 2,4-dinitrobenzyl anion (87116-33-4)

Guidance literature:

With hydroxide; In water; dimethyl sulfoxide; at 25 ℃; Rate constant; variation of solvent systems;

Reference yield:

potassium 2-(2,4-dinitrophenyl)acetate (67099-39-2) → 2,4-dinitrobenzyl anion (87116-33-4)

Guidance literature:

In dimethyl sulfoxide; Ambient temperature; or in THF/18-crown-6;

DOI:10.1021/jo00177a004

Reference yield:

2,4-dinitrotoluene (121-14-2) → 2,4-dinitrobenzyl anion (87116-33-4) + 2,4-DNT (aci-quinoid form) (42849-59-2)

Guidance literature:

In acetonitrile; Product distribution; Mechanism; Irradiation; laser flash photolysis; the absorption spectra and the conductivity changes after the flash was investigated; other solvents;

upstream raw materials:

2,4-dinitrotoluene

potassium 2-(2,4-dinitrophenyl)acetate

Downstream raw materials:

2,4-dinitrotoluene

Refernces

• 1、 McClelland, Robert A.,Steenken, Steen. "Pronounced solvent effect on the absorption spectra of the photochemically produced 2,4-dinitrobenzyl carbanion". . p. 353 - 356. Retrieved 2007/10/02.