Technology Process of (C6H5CH2NC4H7CONC6H4C(CH3)NCH2COO)Ni
There total 1 articles about (C6H5CH2NC4H7CONC6H4C(CH3)NCH2COO)Ni which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium methoxide;
In
methanol;
a mixt. of substituted acetophenone, Ni(NO3)2*6H2O in MeOH, and glycinein MeONa-MeOH was stirred at 40-50°C under Ar, after 1 h the formed ppt. was dissolved by addn. of water, methanolic MeONa was added, reaction was monitored by TLC; 5% aq. CH3COOH was added, mixt. extd. with CHCl3, exts. washed with 5% aq. CH3COOH, evapd. in vacuo, residue dissolved in acetone, hexane was added, pptd. complex filtered;
DOI:10.1021/ja00300a030
- Guidance literature:
-
With
Dowex MSA-I resin;
In
methanol;
a MeOH soln. of Ni-complex was added to Dowex MSA-I resin in BH4(1-) form, mixt. was stirred for 12 h; resin was filtered, reaction products sepd. by preparative TLC on SiO2 (CHCl3-acetone-ethanol); elem. anal.;
DOI:10.1021/ja00300a030
