5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin

Base Information

• Chemical Name: 5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin
• CAS No.: 116206-76-9
• Molecular Formula: C₄₄H₃₂N₆
• Molecular Weight: 644.778
• Mol file: 116206-76-9.mol

Synonyms:5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin

Chemical Property of 5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin

There total 4 articles about 5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

5,10-bis(p-nitrophenyl)-15,20-diphenylporphyrin → 5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin (116206-76-9)

Guidance literature:

With ammonium acetate; zinc; In chloroform; at 20 ℃; for 0.0833333h;

DOI:10.1002/jhet.410

Reference yield:

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → trans-5,15-bis(4-aminophenyl)-10,20-diphenylporphyrin (116206-75-8) + 5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin (116206-76-9)

Guidance literature:

5,15,10,20-tetraphenylporphyrin; With nitric acid; In chloroform; at 20 ℃; for 4h;

With tin(ll) chloride; In hydrogenchloride; at 60 ℃; for 1h;

DOI:10.1002/chem.200600511

Reference yield:

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10-bis(4-aminophenyl)-15,20-diiphenylporphyrin (116206-76-9)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium nitrite; trifluoroacetic acid / 0.03 h / 20 °C

2: tin(II)chloride dihydrate; hydrogenchloride / water / 1.5 h / 65 °C

With hydrogenchloride; tin(II)chloride dihydrate; trifluoroacetic acid; sodium nitrite; In water;

DOI:10.1016/j.molstruc.2017.09.091

upstream raw materials:

5,15,10,20-tetraphenylporphyrin

Downstream raw materials:

C₄₄H₃₀CuN₆