Tetraphenylporphyrin

Base Information

• Chemical Name: Tetraphenylporphyrin
• CAS No.: 917-23-7
• Deprecated CAS: 106051-94-9,15503-35-2,20998-75-8,25323-25-5,87719-36-6,15503-35-2,20998-75-8,25323-25-5,87719-36-6
• Molecular Formula: C44H30N4
• Molecular Weight: 614.749
• Hs Code.: 29349990
• European Community (EC) Number: 213-025-9
• NSC Number: 640184,18506
• UNII: SDB2SH8G5K
• DSSTox Substance ID: DTXSID2061272
• Nikkaji Number: J9.130H
• Wikipedia: Tetraphenylporphyrin
• Metabolomics Workbench ID: 58194
• ChEMBL ID: CHEMBL436524,CHEMBL3039846
• Mol file: 917-23-7.mol

Synonyms:Tetraphenylporphyrin;917-23-7;5,10,15,20-tetraphenylporphyrin;meso-Tetraphenylporphine;meso-Tetraphenylporphyrin;Tetraphenylporphine;5,10,15,20-Tetraphenyl-21H,23H-porphine;21H,23H-Porphine, 5,10,15,20-tetraphenyl-;5,10,15,20-Tetraphenylporphine;meso-Tetraphenylporphyrine;CHEBI:52279;SDB2SH8G5K;20998-75-8;CHEMBL436524;MFCD00011680;NSC 18506;NSC-18506;NSC640184;NSC 640184;NSC-640184;Porphine, 5,10,15,20-tetraphenyl-;(5Z,10Z,14Z,19Z)-5,10,15,20-tetraphenyl-21,23-dihydroporphyrin;2,7,12,17-tetraphenyl-21,22,23,24-tetraazapentacyclo[16.2.1.1^{3,6}.1^{8,11}.1^{13,16}]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene;Tetraphenylporphryin;TPP (chelating agent);TPP;UNII-SDB2SH8G5K;meso-Tetra(phenyl)porphine;SCHEMBL30136;MESO-TETRAPHENYLPORPHIN;5,15,20-Tetraphenylporphine;meso-Tetraphenylporphyrin, 97%;CHEMBL3039846;DTXSID2061272;YNHJECZULSZAQK-LWQDQPMZSA-N;YNHJECZULSZAQK-UHFFFAOYSA-N;Porphine,10,15,20-tetraphenyl-;Tetraphenylporphyrin (Chlorin free);BCP21699;NSC18506;STR04536;BDBM50247512;meso-Tetraphenylporphine, low chlorin;STK569350;5,10,15,20-(tetraphenyl)porphyrin;AKOS002375245;21H, 5,10,15,20-tetraphenyl-;5,10,15,20-tetrakis(phenyl)porphyrin;NCI60_013368;SY009714;HY-103656;.alpha.,.gamma.,.delta.-Tetraphenylporphine;CS-0022009;T1359;Porphine, alpha,beta,gamma,delta-tetraphenyl-;5,10,15,20-Tetraphenyl-21H,23H-prophine;F14722;Porphine, 5,10,15,20-tetraphenyl- (VAN);EN300-7405378;5,10,15,20-tetraphenyl-21,23-dihydroporphyrin;.alpha.,.beta.,.gamma.,.delta.-Tetraphenylporphine;5,10,15,20-Tetraphenyl-21H,23H-porphine, 97%;5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN;5,10,15,20-Tetraphenyl-21H,23H-porphine, >=99%;meso-Tetraphenylporphyrine pound>>5,10,15,20-tetraphenylporphyrin;meso-Tetraphenylporphyrin, suitable for fluorescence, BioReagent, >=99.0% (HPLC)

Chemical Property of Tetraphenylporphyrin

Chemical Property:

• Appearance/Colour: purple glistening crystalline powder
• Melting Point: 300 °C
• Refractive Index: 1.702
• Boiling Point: 648.45°C (rough estimate)
• PSA: 56.30000
• Density: 1.22 g/cm³
• LogP: 6.86620
• Storage Temp.: 2-8°C
• Solubility.: dichloromethane: soluble
• Water Solubility.: Insoluble in water.
• XLogP3: 10.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 614.24704697
• Heavy Atom Count: 48
• Complexity: 851

Purity/Quality:

99% ^*data from raw suppliers

meso-Tetraphenylporphine ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Biological Agents -> Porphyrins
• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)N3

Technology Process of Tetraphenylporphyrin

There total 217 articles about Tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

5,15-dibromo-10,20-diphenylporphyrin (1057140-05-2,151256-86-9) + phenylboronic acid (98-80-6) → 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In N,N-dimethyl-formamide; at 60 ℃; for 3h;

DOI:10.1016/S0040-4039(01)01582-9

Reference yield: 85.5%

5-(2,6-N-dinitrophenyl)-10,15,20-trisphenylporphyrin → 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8)

Guidance literature:

5-(2,6-N-dinitrophenyl)-10,15,20-trisphenylporphyrin; With hydrogenchloride; tin(ll) chloride; In water; at 0 - 20 ℃; for 12h;

With ammonia; In water; pH=10;

Reference yield: 65.0%

benzaldehyde (100-52-7) + 5-phenyldipyrromethane (107798-98-1) → 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8)

Guidance literature:

benzaldehyde; 5-phenyldipyrromethane; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 0.5h;

With selenium(IV) oxide; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1016/j.tetlet.2011.01.044

upstream raw materials:

pyrrole

benzaldehyde

pyridine-4-carbaldehyde

p-benzyloxybenzaldehyde

Downstream raw materials:

meso-tetraphenylchlorin

C₄₆H₃₂N₄O

(5Z,10Z,14Z,19Z)-5,10,15,20-Tetraphenyl-porphyrin; compound with 4-nitro-phenol

N,N'-ethoxymethylene-meso-tetraphenylporphyrin

Refernces

Photocyclization and photooxidation of 3-styrylthiophene

10.1016/S0040-4039(00)00097-6

The study focuses on the photocyclization and photooxidation processes of 3-styrylthiophene, a compound with two isomers: trans-3-styrylthiophene (1) and cis-3-styrylthiophene (2). The research investigates how these isomers react under different photochemical conditions, including in nonpolar and polar solvents, with and without sensitizers. The key findings include that cis-3-styrylthiophene (2) undergoes photochemical cis–trans isomerization and cyclization to form dihydronaphtho-[1,2-b]thiophene (3), with a higher quantum efficiency in nonpolar solvents. Dye-sensitized photooxidation of 3-styrylthiophene results in the production of benzaldehyde and 3-thiophenecarboxaldehyde, and the process is suggested to occur via a superoxide radical anion pathway rather than through singlet oxygen. Additionally, auto-photooxidation in the presence of oxygen leads to photocyclization, oxidation, and dimerization products. The study proposes that these reactions may involve the formation of a charge transfer complex between oxygen and the substrate. The research is significant for understanding the behavior of polythiophenes, which are important for the production of conductive polymers, and could contribute to improving the photostability of these materials.

Self-assembly of supramolecular oligo-phenylene-ethynylene wires consisting of double Hamilton receptor modified OPE rods and a tetraphenylporphyrin cyanurate

10.1016/j.tet.2008.08.054

This research describes the synthesis, characterization, and self-assembly of supramolecular oligo-phenylene-ethynylene (OPE) wires, which are bridged bis-Hamilton receptors, and their interaction with a cyanuric acid-modified tetraphenylporphyrin (TPP). The purpose of the study was to investigate the electronic, photoluminescence, and electroluminescence properties of these π-conjugated systems, which are relevant for their potential use as nanowires between electrodes. The researchers synthesized new OPE bridged bis-Hamilton receptors and characterized their linear H-bonding behavior with the modified TPP. The resulting complexes were analyzed using 1H NMR, UV/vis, and fluorescence spectroscopies, and the association constants and cooperativity of binding were determined. The study concluded that the self-assembled structures formed 1:2 complexes with strong association constants, indicating a robust supramolecular interaction. No electronic communication was detected between the OPE wires and the porphyrin, suggesting that OPEs can serve as inactive bridges in supramolecular donor-acceptor arrays. Key chemicals used in the process included 5-iodo-xylene, KMnO4, thionyl chloride, aminopyridine derivatives, trimethylsilylacetylene, TBAF, and various catalysts and solvents for the coupling and deprotection reactions.

SYNTHESE ET CARACTERISATION PAR RMN 1H D'ALKYL(ARYL)FERRIPORPHYRINES A LIAISON ? METAL-CARBONE

10.1016/0022-328X(83)80109-0

The research focuses on the synthesis and characterization of a series of alkyl(aryl)iron(III) porphyrins with a metal-carbon bond. The purpose of this study is to explore the synthesis of these metalloporphyrin complexes, which are of significant interest due to their potential role in the metabolism of certain polyhalogenated compounds by cytochrome P450 in the liver. The researchers synthesized these complexes using two main methods: the reaction of organomagnesium compounds with iron(III) chloride porphyrins and oxidative addition of alkyl halides to iron(I) porphyrins. Key chemicals used in the research include various porphyrin derivatives such as octaethylporphyrin (OEP), tetraphenylporphyrin (TPP), and their substituted forms, along with organomagnesium compounds like RMgX, and alkyl halides. The synthesized complexes were characterized using 1H NMR spectroscopy, which provided detailed information about the structure and environment of the protons in the porphyrin ring and the axial ligands. The study concludes that the synthesized alkyl(aryl)iron(III) porphyrins exhibit distinct spectroscopic characteristics, with the alkyl derivatives showing a more shielded environment for the protons compared to the aryl derivatives. The results also suggest a significant delocalization of spin from the metal to the axial ligand, indicating a strong interaction between the metal and the ligand. The findings contribute to a better understanding of the structure and properties of these metalloporphyrin complexes, which could have implications for their biological and chemical applications.

Electron paramagnetic resonance spectroscopy as a probe of hydrogen bonding in heme-Thiolate proteins

10.1021/acs.inorgchem.9b02506

The research investigates the hydrogen bonding environment surrounding the Fe-coordinating thiolate in heme-thiolate proteins using electron paramagnetic resonance (EPR) spectroscopy. The study synthesizes and characterizes a series of six-coordinate, aryl-thiolate-ligated Fe(III) porphyrin complexes with tunable intramolecular hydrogen bonds. Key chemicals involved include various thiol ligand precursors such as 2,2′-disulfanediylbis(N-phenylbenzamide) and its derivatives with different para substituents (e.g., methyl, hydrogen, chlorine, trifluoromethyl, nitro), as well as tetraphenylporphyrin (TPP) complexes. The researchers used these chemicals to create model compounds that mimic the hydrogen bonding interactions in heme-thiolate proteins, allowing them to explore how changes in hydrogen bonding strength affect the electronic structure and EPR signals of these complexes. The findings establish EPR spectroscopy as a valuable tool for studying the influence of second coordination sphere effects on heme-thiolate protein function.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 917-23-7 Tetraphenylporphyrin

Send

Send

Metric Ton KG G Pound L ML

Send

Send