Phenylsulfonyle-2 heptene-6-oate de methyle

Base Information

• Chemical Name: Phenylsulfonyle-2 heptene-6-oate de methyle
• CAS No.: 133124-32-0
• Molecular Formula: C₁₄H₁₈O₄S
• Molecular Weight: 282.361
• Mol file: 133124-32-0.mol

Synonyms:Phenylsulfonyle-2 heptene-6-oate de methyle

Chemical Property of Phenylsulfonyle-2 heptene-6-oate de methyle

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenylsulfonyle-2 heptene-6-oate de methyle

There total 2 articles about Phenylsulfonyle-2 heptene-6-oate de methyle which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

methyl benzenesulfonylacetate (34097-60-4) + bromopentene (1119-51-3) → Phenylsulfonyle-2 heptene-6-oate de methyle (133124-32-0)

Guidance literature:

With potassium hydride; In N,N-dimethyl-formamide; Ambient temperature;

DOI:10.1021/jo982088t

Reference yield:

1-iodo-4-pentene (7766-48-5) + methyl benzenesulfonylacetate (34097-60-4) → Phenylsulfonyle-2 heptene-6-oate de methyle (133124-32-0)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; 1.) room temp., 20 min, 2.) 50-60 deg C, 12 h;

DOI:10.1021/jo00077a043

Reference yield: 94.5%

Phenylsulfonyle-2 heptene-6-oate de methyle (133124-32-0) + methyl iodide (74-88-4) → Methyl (+/-)-2-methyl-2-(phenylsulfonyl)-6-heptenoate (153165-42-5)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; 1.) 45 min, 2.) 50-60 deg C, overnight;

DOI:10.1021/jo00077a043

upstream raw materials:

1-iodo-4-pentene

methyl benzenesulfonylacetate

bromopentene

Downstream raw materials:

1-Methoxycarbonyl-2-benzyl-phenylsulfonyl-cyclopentane

Methyl (+/-)-2-methyl-2-(phenylsulfonyl)-6-heptenoate

1-Ethyl methyl (+/-)-(E)-7-methyl-7-(phenylsulfonyl)-2-octenedioate