cobalt(III)-tetrakis(4-sulfonatophenyl)porphyrin

Base Information

• Chemical Name: cobalt(III)-tetrakis(4-sulfonatophenyl)porphyrin
• CAS No.: 91629-46-8
• Molecular Formula: C₄₄H₂₄CoN₄O₁₂S₄
• Molecular Weight: 987.951
• Mol file: 91629-46-8.mol

Synonyms:Cobaltate(3-),[[4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis[benzenesulfonato]](6-)-N21,N22,N23,N24]-,(SP-4-1)-; Benzenesulfonic acid,4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, cobalt complex

Chemical Property of cobalt(III)-tetrakis(4-sulfonatophenyl)porphyrin

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 312.82000
• Density: g/cm³
• LogP: 6.06400

Purity/Quality:

Safty Information:

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Technology Process of cobalt(III)-tetrakis(4-sulfonatophenyl)porphyrin

There total 2 articles about cobalt(III)-tetrakis(4-sulfonatophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrasodium (5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinato)cobalt(II) → {Co(III)(tetrakis(4-sulfonatophenyl)porphyrin)}(3-) (91629-46-8)

Guidance literature:

With air; In hydrogenchloride; air oxidn. of cobalt complex in aq. HCl; pptn. in acetone, drying in vac. for 12 h, cation exchange chromy (Amberlite GC120, Na(1+) form);

DOI:10.1039/b006619m

Reference yield:

Na[Co(5,10,15,20-tetra(p-sulfophenyl)porphine)]*8H2O → {Co(III)(tetrakis(4-sulfonatophenyl)porphyrin)}(3-) (91629-46-8)

Guidance literature:

With oxygen; hydrogen cation; In water; byproducts: H2O; Irradiation (UV/VIS); product was not isolated; UV; Kinetics;

DOI:10.1246/bcsj.54.413

Reference yield:

{Co(III)(tetrakis(4-sulfonatophenyl)porphyrin)}(3-) (91629-46-8) + nitrogen(II) oxide (10102-43-9) → Co(NO)(tetrameso(4-sulfonatophenyl)porphinate)(3-)

Guidance literature:

With phosphate buffer; In water; pH 7 (phosphate buffer) under NO (1 atm) for 10-15 min at room temp.; not isolatrd; prepn. in situ;

DOI:10.1021/ja0113910

Downstream raw materials:

Co(III)TPPS-Co(III)TMPyP

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