1-O-(4-hydroxybenzoyl)-β-D-glucopyranose

Base Information

• Chemical Name: 1-O-(4-hydroxybenzoyl)-β-D-glucopyranose
• CAS No.: 25545-07-7
• Molecular Formula: C₁₃H₁₆O₈
• Molecular Weight: 300.265
• Mol file: 25545-07-7.mol

Synonyms:1-O-(4-hydroxybenzoyl)-β-D-glucopyranose

Chemical Property of 1-O-(4-hydroxybenzoyl)-β-D-glucopyranose

Chemical Property:

Purity/Quality:

98.0% ^*data from raw suppliers

1-(4-Hydroxybenzoyl)glucose 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O-(4-hydroxybenzoyl)-β-D-glucopyranose

There total 10 articles about 1-O-(4-hydroxybenzoyl)-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-acetyloxy-benzoic acid (2345-34-8) + 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → 1-O-(4-hydroxybenzoyl)-β-D-glucopyranose (25545-07-7)

Guidance literature:

4-acetyloxy-benzoic acid; 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide; With potassium hydroxide; In water; acetone; at -20 - 20 ℃; for 5h; Inert atmosphere;

With methanol; sodium methylate; at 0 - 20 ℃; for 3h;

Reference yield:

UDP-glucose (133-89-1) + 4-hydroxy-benzoic acid (99-96-7) → 1-O-(4-hydroxybenzoyl)-β-D-glucopyranose (25545-07-7)

Guidance literature:

With glycosylation enzyme transformed with DcUGTA₈₂; at 30 ℃; for 3h; Enzymatic reaction;

Reference yield:

4-Benzoyloxy-benzoic acid (4aR,6S,7R,8R,8aS)-7,8-dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester → 1-O-(4-hydroxybenzoyl)-β-D-glucopyranose (25545-07-7)

Guidance literature:

With hydrogen; acetic acid; palladium on activated charcoal; In ethanol; ethyl acetate; at 40 ℃; for 4h;

DOI:10.1016/0031-9422(88)80121-3

upstream raw materials:

4-hydroxy-benzoic acid

D-glucose

4-(benzoyloxy)benzoyl chloride

benzoyl chloride

Downstream raw materials:

3,5-di-O-β-D-glucopyranoside of cyanidin