4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

Base Information

Chemical Name:4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone
CAS No.:1360607-20-0
Molecular Formula:C₁₅H₂₂BFN₂O₂
Molecular Weight:292.161
Hs Code.:

Synonyms:4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

Suppliers and Price of 4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

There total 4 articles about 4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 155140-69-5
4-fluorobenzaldehyde N,N-dimethylhydrazone

: 73183-34-3
bis(pinacol)diborane

: 1360607-20-0
4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

Guidance literature:: With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; N,N-dibenzyl-N'-(pyridin-2-ylmethylene)hydrazine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; In tetrahydrofuran; at 80 ℃; for 7h; regioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201104544

Reference yield: 70.0%

: 155140-69-5
4-fluorobenzaldehyde N,N-dimethylhydrazone

: 73183-34-3
bis(pinacol)diborane

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1360607-20-0
4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

Guidance literature:: With cat. [Ir(μ-OCH3)(C8H12)]2/2-C5H4NCHNN(CH2C6H5)2; In tetrahydrofuran; Sonication; dried Schlenk tube charged with dimethylhydrazone and diboron compd., added catalyst stock soln. (prepd. by sonication for 1 h) and pinacolborane, stirred at 80°C for 7 h; cooled to room temp., concd. to dryness, purified by column chromy. on neutral alumina (n-hexane/CH3COOC2H5);
DOI:10.1002/anie.201104544

Reference yield:

: 155140-69-5
4-fluorobenzaldehyde N,N-dimethylhydrazone

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1360607-20-0
4-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde N,N-dimethylhydrazone

Guidance literature:: With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4-(dimethylamino)picolinaldehyde N,N-dibenzylhydrazone; In tetrahydrofuran; at 80 ℃; regioselective reaction; Inert atmosphere;
DOI:10.1021/jo301965v