(R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate

Base Information

Chemical Name:(R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate
CAS No.:1528757-97-2
Molecular Formula:C₃₂H₄₆O₅Si
Molecular Weight:538.8
Hs Code.:

Synonyms:(R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate

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Technology Process of (R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate

There total 11 articles about (R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 10353-53-4
1,2-epoxy-5-hexene

: 442913-57-7
(R)-2-(methoxymethoxy)hex-5-enoic acid

: 1528757-97-2
(R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate

Guidance literature:: With dmap; 2,4,6-trichlorobenzoyl chloride; triethylamine; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/j.bmcl.2013.11.010

Reference yield: 98.0%

: 1528757-96-1
(4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-ol

: 442913-57-7
(R)-2-(methoxymethoxy)hex-5-enoic acid

: 1528757-97-2
(R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate

Guidance literature:: With dmap; 2,4,6-trichlorobenzoyl chloride; triethylamine; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/j.bmcl.2013.11.010

Reference yield:

: 133494-68-5
(R)-1,2-dihydroxy-5-hexene

: 1528757-97-2
(R)-((4R,5S)-5-(tert-butyldiphenylsilyloxy)oct-7-en-4-yl) 2-(methoxymethoxy)hex-5-enoate

Guidance literature:: Multi-step reaction with 5 steps

1: 1H-imidazole / tetrahydrofuran / 20 °C

2: N-ethyl-N,N-diisopropylamine / dichloromethane / 45 °C

3: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 °C

4: [bis(acetoxy)iodo]benzene; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / water; acetonitrile / 3 h / 20 °C

5: triethylamine; 2,4,6-trichlorobenzoyl chloride; dmap / tetrahydrofuran / 20 °C

With 1H-imidazole; dmap; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; 2,4,6-trichlorobenzoyl chloride; tetrabutyl ammonium fluoride; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1016/j.bmcl.2013.11.010