methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate

Base Information

Chemical Name:methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate
CAS No.:155877-81-9
Molecular Formula:C₃₀H₃₄N₂O₃
Molecular Weight:470.612
Hs Code.:

Synonyms:methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate

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Chemical Property of methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate

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Technology Process of methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate

There total 9 articles about methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 7377-26-6
4-Methoxycarbonylbenzoyl chloride

: 155877-79-5
N-methyl-N-phenyl-5,6,7,8-tetrahydro-5,5,8,8-tetramethylnaphthalene-2,3-diamine

: 155877-81-9
methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate

Guidance literature:: With pyridine; In benzene; for 1h;
DOI:10.1021/jm00036a017

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 155877-81-9
methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate

Guidance literature:: Multi-step reaction with 4 steps

1: 48 percent / K₂CO₃, CuI / 12 h / 180 °C

2: 1.) NaH / 1.) DMF, 20 min, 2.) DMF, 20 min

3: 53 percent / Fe, aq. HCl / ethanol / 1 h / Heating

4: 83 percent / pyridine / benzene / 1 h

With pyridine; hydrogenchloride; copper(l) iodide; iron; sodium hydride; potassium carbonate; In ethanol; benzene;
DOI:10.1021/jm00036a017

Reference yield:

: 6223-78-5
2,5-dichloro-2,5-dimethyl hexane

: 155877-81-9
methyl 4-<<5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-3-(N-methyl-N-phenylamino)-2-naphthalenyl>carbamoyl>benzoate

Guidance literature:: Multi-step reaction with 7 steps

1: 55 percent / AlCl₃ / CH₂Cl₂ / 0.33 h / 0 °C

2: 52 percent / KNO₃, trifluoromethanesulfonic acid / 1.5 h / Ambient temperature

3: 99 percent / 2 N aq. NaOH / ethanol / 2 h / Heating

4: 48 percent / K₂CO₃, CuI / 12 h / 180 °C

5: 1.) NaH / 1.) DMF, 20 min, 2.) DMF, 20 min

6: 53 percent / Fe, aq. HCl / ethanol / 1 h / Heating

7: 83 percent / pyridine / benzene / 1 h

With pyridine; hydrogenchloride; sodium hydroxide; copper(l) iodide; aluminium trichloride; trifluorormethanesulfonic acid; iron; sodium hydride; potassium carbonate; potassium nitrate; In ethanol; dichloromethane; benzene;
DOI:10.1021/jm00036a017