tetramethyl titanium

Base Information

• Chemical Name: tetramethyl titanium
• CAS No.: 2371-70-2
• Molecular Formula: C₄H₁₂Ti
• Molecular Weight: 108.019
• Mol file: 2371-70-2.mol

Synonyms:tetramethyl titanium

Chemical Property of tetramethyl titanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetramethyl titanium

There total 1 articles about tetramethyl titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyllithium (917-54-4) + dimethyldichlorotitanium(IV) (35739-70-9) → tetramethyl titanium (2371-70-2)

Guidance literature:

at -80 - -60 ℃; for 4h;

DOI:10.1039/d0cc05816e

Reference yield: 63.0%

N,N,N'-tris(trimethylsilyl)benzamidine (119921-07-2) + tetramethyl titanium (2371-70-2) → bis[N,N'-bis(trimethylsilyl)benzamidinato]dimethyltitanium

Guidance literature:

In diethyl ether; pentane; byproducts: CH4; Ar atm.; cooling (-78°C), heating to room temp.; evapn. (vac.), extraction (toluene), crystn. (-78°C, several days), drying (vac.); elem. anal.;

DOI:10.1002/zaac.19966220424

Reference yield: 62.5%

N,N,N',N'-tetrabenzyl-ethane-1,2-diamine (57693-32-0) + tetramethyl titanium (2371-70-2) → (CH3)4Ti((C6H5CH2)2NC2H4N(CH2C6H5)2)

Guidance literature:

In diethyl ether; addn. of tetrabenzylethylenediamine to a soln. of Me4Ti in Et2O at -30°C; evapn. of solvent in vac. at -30°C;; dissolving residue in cold n-pentane/Et2O (1:1), filtering; cooling to -78°C; crystn. after several days; filtration at -78°C; drying at -30°C in vac.; elem. anal.;;

upstream raw materials:

methyllithium

dimethyldichlorotitanium(IV)

Downstream raw materials:

(R)-2-nonanol

(S)-nonan-2-ol

(1RS,2SR)-(+/-)-1,2-diphenyl-1,2-propandiol

(S)-1-(1-Naphthyl)ethanol