Methyl 5-formyl-2-nitrobenzoate

Base Information

Chemical Name:Methyl 5-formyl-2-nitrobenzoate
CAS No.:133719-04-7
Molecular Formula:C₉H₇NO₅
Molecular Weight:209.158
Hs Code.:
European Community (EC) Number:894-584-1

Synonyms:methyl 5-formyl-2-nitrobenzoate;133719-04-7;methyl5-formyl-2-nitrobenzoate;SCHEMBL2772097;MFCD26863462;CS-0197799;EN300-2295744;Z1650063189

Suppliers and Price of Methyl 5-formyl-2-nitrobenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Alichem
Methyl5-formyl-2-nitrobenzoate
10g
$ 915.84

Alichem
Methyl5-formyl-2-nitrobenzoate
5g
$ 587.52

Alichem
Methyl5-formyl-2-nitrobenzoate
1g
$ 211.20

Total 6 raw suppliers

Chemical Property of Methyl 5-formyl-2-nitrobenzoate

Chemical Property:

XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:209.03242232
Heavy Atom Count:15
Complexity:272

Purity/Quality:

99%, ^*data from raw suppliers

Methyl5-formyl-2-nitrobenzoate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C1=C(C=CC(=C1)C=O)[N+](=O)[O-]

Technology Process of Methyl 5-formyl-2-nitrobenzoate

There total 5 articles about Methyl 5-formyl-2-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 133719-03-6
5-hydroxymethyl-2-nitro-benzoic acid methyl ester

: 133719-04-7
5-formyl-2-nitro-benzoic acid methyl ester

Guidance literature:: With aluminum oxide; pyridinium chlorochromate; In dichloromethane; at 0 ℃; for 18h;
DOI:10.1021/jm970704s

Reference yield: 40.0%

: 1360148-36-2
5-dibromomethyl-2-nitro-benzoic acid methyl ester

: 133719-04-7
5-formyl-2-nitro-benzoic acid methyl ester

Guidance literature:: With calcium carbonate; In water; for 24h; Reflux;
DOI:10.5012/bkcs.2011.32.12.4309

Reference yield:

: 64152-09-6
3-Methoxycarbonyl-4-nitrobenzoic acid

: 133719-04-7
5-formyl-2-nitro-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / BH₃*methyl sulfide / tetrahydrofuran / 5 h / Heating

2: 94 percent / PCC, neutral activity I Al₂O₃ / CH₂Cl₂ / 18 h / 0 °C

With aluminum oxide; dimethylsulfide borane complex; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jm970704s