5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one

Base Information

Chemical Name:5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one
CAS No.:1246840-48-1
Molecular Formula:C₅₁H₄₄O₁₂
Molecular Weight:848.903
Hs Code.:

Synonyms:5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one

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Chemical Property of 5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one

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Technology Process of 5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one

There total 8 articles about 5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 67-64-1
acetone

: 477244-20-5
2-(2,2-diphenylbenzo[1,3]dioxol-5-yl)-3-β-D-glucopyranosyloxy-5,7-bisbenzyloxy-4H-chromen-4-one

5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one: 1246840-48-1
5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one

Guidance literature:: With sulfuric acid; copper(II) sulfate; at 20 ℃; for 24h; Sealed vial;
DOI:10.1016/j.bmcl.2010.02.060

Reference yield:

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one: 1246840-48-1
5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate / acetone / 12 h / 40 °C / Inert atmosphere

2: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C

3: sodium methylate; methanol / ethyl acetate / 0.5 h / 20 °C

4: sulfuric acid; copper(II) sulfate / 48 h / 20 °C / Sealed tube

With methanol; sodium methylate; potassium carbonate; sulfuric acid; copper(II) sulfate; In ethyl acetate; N,N-dimethyl-formamide; acetone;

Reference yield:

: 604-69-3
β-D-glucose pentaacetate

5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one: 1246840-48-1
5,7-dibenzyloxy-2-(2,2-diphenylbenzo[d][1,3]dioxol-5-yl)-3-β-D-(4'',6''-O-isopropylidene)glucosyl-4H-chromen-4-one

Guidance literature:: Multi-step reaction with 5 steps

1: hydrogen bromide; acetic acid / 2 h / 20 °C

2: potassium carbonate / acetone / 12 h / 40 °C / Inert atmosphere

3: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C

4: sodium methylate; methanol / ethyl acetate / 0.5 h / 20 °C

5: sulfuric acid; copper(II) sulfate / 48 h / 20 °C / Sealed tube

With methanol; hydrogen bromide; sodium methylate; potassium carbonate; acetic acid; sulfuric acid; copper(II) sulfate; In ethyl acetate; N,N-dimethyl-formamide; acetone;