[Ti(CH₂CMe₃)(P(2,4,6-(C(CH₃)3)3C₆H₂)((2,6-(CH(CH₃)2)2C₆H₃)NC(Me)CHC(Me)N(2,6-(CH(CH₃)2)2C₆H₃))]

Base Information

• Chemical Name: [Ti(CH₂CMe₃)(P(2,4,6-(C(CH₃)3)3C₆H₂)((2,6-(CH(CH₃)2)2C₆H₃)NC(Me)CHC(Me)N(2,6-(CH(CH₃)2)2C₆H₃))]
• CAS No.: 606968-40-5
• Molecular Formula: C₅₂H₈₁N₂PTi
• Molecular Weight: 813.082
• Mol file: 606968-40-5.mol

Synonyms:[Ti(CH₂CMe₃)(P(2,4,6-(C(CH₃)3)3C₆H₂)((2,6-(CH(CH₃)2)2C₆H₃)NC(Me)CHC(Me)N(2,6-(CH(CH₃)2)2C₆H₃))]

Chemical Property of [Ti(CH₂CMe₃)(P(2,4,6-(C(CH₃)3)3C₆H₂)((2,6-(CH(CH₃)2)2C₆H₃)NC(Me)CHC(Me)N(2,6-(CH(CH₃)2)2C₆H₃))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ti(CH₂CMe₃)(P(2,4,6-(C(CH₃)3)3C₆H₂)((2,6-(CH(CH₃)2)2C₆H₃)NC(Me)CHC(Me)N(2,6-(CH(CH₃)2)2C₆H₃))]

There total 1 articles about [Ti(CH₂CMe₃)(P(2,4,6-(C(CH₃)3)3C₆H₂)((2,6-(CH(CH₃)2)2C₆H₃)NC(Me)CHC(Me)N(2,6-(CH(CH₃)2)2C₆H₃))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

nacnacTi(CHtBu)(OTf) + lithium 2,4,6-tris(tert-butyl)phenylphosphide (83115-13-3) → [Ti(CH2CMe3)(P(2,4,6-(C(CH3)3)3C6H2)((2,6-(CH(CH3)2)2C6H3)NC(Me)CHC(Me)N(2,6-(CH(CH3)2)2C6H3))] (606968-40-5)

Guidance literature:

In pentane; addn. of 1 equiv. of LiPHC6H2(C(CH3)3)3 to soln. of Ti(CHCMe3)(OTf)(N(C6H3(CHMe2)2)C(Me)CHC(Me)N(C6H3(Me2CH)2) in pentane at -35°C; monitoring by NMR;

DOI:10.1021/ja036559r

Reference yield: 68.0%

[Ti(CH2CMe3)(P(2,4,6-(C(CH3)3)3C6H2)((2,6-(CH(CH3)2)2C6H3)NC(Me)CHC(Me)N(2,6-(CH(CH3)2)2C6H3))] (606968-40-5) + diazodiphenylmethane (908093-98-1) → (2,6-(i-Pr)2C6H3NC(Me)CHC(Me)NC6H3(i-Pr)2-2,6)Ti(NP(CH2-t-Bu)C6H2(t-Bu)3-2,4,6)(NCPh2) (677716-04-0)

Guidance literature:

In pentane; ligand added slowly to pentane soln. of Ti complex; recrystd. from pentane at -35°C;

DOI:10.1039/b311748k

Reference yield: 60.0%

[Ti(CH2CMe3)(P(2,4,6-(C(CH3)3)3C6H2)((2,6-(CH(CH3)2)2C6H3)NC(Me)CHC(Me)N(2,6-(CH(CH3)2)2C6H3))] (606968-40-5) + tert-butylisonitrile (119072-55-8,7188-38-7) → (η1-2,6-(i-Pr)2C6H3NC(Me)CHC(Me)NC6H3(i-Pr)2-2,6)Ti(CN-t-Bu)(η2-(N,C)-t-BuNCCH2-t-Bu)(η2-(N,C)-t-BuNCPC6H2(t-Bu)3) (677716-02-8)

Guidance literature:

In pentane; pentane soln. of Ti complex treated with CN-t-Bu (3 equiv.); recrystd. from pentane;

DOI:10.1039/b311748k

upstream raw materials:

lithium 2,4,6-tris(tert-butyl)phenylphosphide

Downstream raw materials:

(η1-2,6-(i-Pr)2C6H3NC(Me)CHC(Me)NC6H3(i-Pr)2-2,6)Ti(CN-t-Bu)(η2-(N,C)-t-BuNCCH2-t-Bu)(η2-(N,C)-t-BuNCPC6H2(t-Bu)3)

(2,6-(i-Pr)2C₆H₃NC(Me)CHC(Me)NC₆H₃(i-Pr)2-2,6)Ti(NP(CH₂-t-Bu)C₆H₂(t-Bu)3-2,4,6)(NCPh₂)