tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate

Base Information

Chemical Name:tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate
CAS No.:1352739-57-1
Molecular Formula:C₁₇H₂₄O₄
Molecular Weight:292.375
Hs Code.:

Synonyms:tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate

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Chemical Property of tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate

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Technology Process of tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate

There total 5 articles about tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 24424-99-5
di-tert-butyl dicarbonate

: 1352739-55-9
4-[(4-methoxybenzyl)oxy]-2-methylenebutanoic acid

: 1352739-57-1
tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate

Guidance literature:: With dmap; In tert-butyl alcohol; at 20 ℃; for 8h; Inert atmosphere;
DOI:10.1002/ejoc.201100669

Reference yield:

: 250209-01-9
4-hydroxy-2-methylenebutanal

: 1352739-57-1
tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate

Guidance literature:: Multi-step reaction with 3 steps

1: camphor-10-sulfonic acid / dichloromethane; cyclohexane / 10 h / Inert atmosphere

2: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / tetrahydrofuran; water; acetic acid; tert-butyl alcohol / 4 h / 20 °C / Inert atmosphere

3: dmap / tert-butyl alcohol / 8 h / 20 °C / Inert atmosphere

With dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; camphor-10-sulfonic acid; In tetrahydrofuran; dichloromethane; cyclohexane; water; acetic acid; tert-butyl alcohol; 2: Pinnick reaction;
DOI:10.1002/ejoc.201100669

Reference yield:

: 55881-94-2
3-methylene-1,4-dihydroxybutane

: 1352739-57-1
tert-butyl 4-[(4-methoxybenzyl)oxy]-2-methylenebutanoate

Guidance literature:: Multi-step reaction with 4 steps

1: oxygen; palladium diacetate; triethylamine / tetrahydrofuran; toluene

2: camphor-10-sulfonic acid / dichloromethane; cyclohexane / 10 h / Inert atmosphere

3: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / tetrahydrofuran; water; acetic acid; tert-butyl alcohol / 4 h / 20 °C / Inert atmosphere

4: dmap / tert-butyl alcohol / 8 h / 20 °C / Inert atmosphere

With dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; camphor-10-sulfonic acid; oxygen; palladium diacetate; triethylamine; In tetrahydrofuran; dichloromethane; cyclohexane; water; acetic acid; toluene; tert-butyl alcohol; 3: Pinnick reaction;
DOI:10.1002/ejoc.201100669