(2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

Base Information

Chemical Name:(2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran
CAS No.:1357384-44-1
Molecular Formula:C₂₀H₂₈O₃
Molecular Weight:316.441
Hs Code.:

Synonyms:(2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

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Technology Process of (2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

There total 3 articles about (2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 111-34-2,92680-80-3
-butyl vinyl ether

: 197379-09-2
(1R,3R,5S)-3-Benzyloxy-8-oxa-bicyclo[3.2.1]oct-6-ene

: 1357384-44-1
(2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

Guidance literature:: With Mo(N-1-adamantyl)(CHCMe₂Ph)(2,5-dimethylpyrrolide)₂; (R)-3,3'-Dibromo-2'-(tert-butyldimethylsilyloxy)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol; In benzene; at 22 ℃; optical yield given as %ee; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ja210946z

Reference yield:

: 111-34-2,92680-80-3
-butyl vinyl ether

: 197379-09-2
(1R,3R,5S)-3-Benzyloxy-8-oxa-bicyclo[3.2.1]oct-6-ene

: (2R,4R,6S)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

: 1357384-44-1
(2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

Guidance literature:: With Mo(N-1-adamantyl)(CHCMe₂Ph)(2,5-dimethylpyrrolide)₂; (R)-3,3'-Dibromo-2'-(tert-butyldimethylsilyloxy)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol; In benzene; at 22 ℃; for 0.5h; optical yield given as %ee; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ja210946z

Reference yield:

: 111-34-2,92680-80-3
-butyl vinyl ether

: 139882-20-5
3α-Benzyloxy-(1-αH,5-αH)-8-oxabicyclo<3.2.1>oct-6-en

: (2R,4R,6S)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

: 1357384-44-1
(2S,4S,6R)-4-(benzyloxy)-2-((Z)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

: (2S,4S,6R)-4-(benzyloxy)-2-((E)-2-butoxyvinyl)-6-vinyltetrahydro-2H-pyran

Guidance literature:: -butyl vinyl ether; With C₅₂H₄₇IN₂O₂Ru; for 0.5h; Inert atmosphere;

3α-Benzyloxy-(1-αH,5-αH)-8-oxabicyclo<3.2.1>oct-6-en; In benzene; at 22 ℃; for 24h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja304827a