dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II)

Base Information

• Chemical Name: dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II)
• CAS No.: 35273-41-7
• Molecular Formula: C₂₄H₁₆Cl₂N₂Pt
• Molecular Weight: 598.39
• Mol file: 35273-41-7.mol

Synonyms:dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II)

Chemical Property of dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II)

There total 6 articles about dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

dichlorobis(dimethylsulfoxide)platinum(II) (30729-25-0,25794-47-2,15274-33-6,22840-91-1,75992-73-3,14568-13-9) + bathophenanthroline (1662-01-7) → dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II) (35273-41-7)

Guidance literature:

In methanol; for 3h; Reflux;

DOI:10.1039/c3cc40868j

Reference yield: 90.0%

dichlorobis(dimethyl sulfoxide)platinum(II) + bathophenanthroline (1662-01-7) → dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II) (35273-41-7)

Guidance literature:

In methanol; dropwise addn. of equimolar amt. of phen derivative to Pt-complex suspn., stirring for 12 h; collection (filtration), washing (MeOH, Et2O), drying in air;

DOI:10.1021/ic960125y

Reference yield: 89.0%

aquapentachloroplatinic acid di(18-crown-6) hexahydrate + bathophenanthroline (1662-01-7) → dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II) (35273-41-7)

Guidance literature:

With H₂O; In methanol; Irradiation (UV/VIS); soln. of Pt compd. in MeOH added to soln. of N compd. in MeOH, water added, stirred at 40°C for 10-30 h with UV irradiation; filtered, washed with MeOH, dried in vac., elem. anal.;

DOI:10.1002/zaac.200390119

upstream raw materials:

potassium tetrachloroplatinate(II)

bathophenanthroline

dichlorobis(dimethylsulfoxide)platinum(II)

Downstream raw materials:

{Pt(4,7-diphenyl-1,10-phenanthroline)(DHN)}

PtBr₂(4,7-diphenyl-1,10-phenanthroline)

PtCl₂(4,7-diphenyl-1,10-phenanthroline)^(1-)

4,7-diphenyl-1,10-phenanhroline bis-4-tert-butylphenolateplatinum(II)