2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane

Base Information

• Chemical Name: 2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane
• CAS No.: 1133798-55-6
• Molecular Formula: C₂₄H₁₈B₃Cl₃O₃
• Molecular Weight: 493.197
• Mol file: 1133798-55-6.mol

Synonyms:2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane

Chemical Property of 2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane

There total 1 articles about 2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-4-chlorostyrylboronic acid (154230-29-2) → 2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane (1133798-55-6)

Guidance literature:

In toluene; for 3h; Inert atmosphere; Reflux;

DOI:10.1021/ol900362d

Reference yield:

2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane (1133798-55-6) + N,N-diisopropyl-α-diazoacetamide (107245-12-5) → (E)-4-(4-chlorophenyl)-N,N-diisopropylbut-3-enamide (1133798-50-1)

Guidance literature:

With diisopropylamine; In 1,2-dichloro-ethane; at 100 ℃; for 10h; Inert atmosphere;

DOI:10.1021/ol900362d

Reference yield:

ethanol (64-17-5) + 2,2,2-trifluorodiazoethane (371-67-5) + 2,4,6-tris((E)-4-chlorostyryl)-1,3,5,2,4,6-trioxatriborinane (1133798-55-6) → C14H17BClF3O2

Guidance literature:

With (R)-3,3’-dibromo-5,5’,6,6’,7,7’,8,8’-octahydro-[1,1’-binaphthalene]-2,2’-diol; In dichloromethane; at 40 ℃; for 48h; Inert atmosphere; Glovebox; Molecular sieve;

DOI:10.1021/jacs.0c09923

upstream raw materials:

(E)-4-chlorostyrylboronic acid

Downstream raw materials:

(E)-4-(4-chlorophenyl)-N,N-diisopropylbut-3-enamide